Electrochemical Properties and Synthesis of Poly(ether)tailed Cobalt(II)bipyridine Complex

폴리(에테르)사슬이 결합된 Cobalt(II)bipyridine 착물의 합성과 전기화학적 성질

  • Kim, II Kwang (Dept. of Chemistry, Wonkwang Univ.) ;
  • Jun, II Chul (Dept. of Chemistry, Univ. of Jeonbuk) ;
  • Murray, Royce W. (Dept. of Chemistry, Univ. of North Carolina)
  • 김일광 (원광대학교 자연대 화학과) ;
  • 전일철 (전북대학교 자연대 화학과) ;
  • Received : 1996.07.26
  • Published : 1996.09.25

Abstract

The synthesis of poly(ether)tailed bipyridine complex as redox reaction probes has advanced attempts to interpret very slow diffusion and heterogeneous electron transfer. Diffusion coefficients as low as $1.5{\times}10^{-15}cm^2/s$ have been observed for the oxidation of neat $Co(bpy(ppgm)_2)_{3^-}(ClO_4)_2$ with $LiClO_4$ electrolyte. Heterogeneous electron transfer rate constants of materials were found to vary with diffusion coefficient. The decrease in k as the diffusion coefficient decreases was actually caused by the decreasing D. Diffusion coefficient for compound of strong ion pairing anion($ClO{_4}^-$) was much smaller than the diffusion coefficient for compound of weak ion pairing anion($CF_3COO^-$).

Acknowledgement

Supported by : 교육부