Synthesis of Ultrathin Polymer Films by Self Assembly

자기 집합에 의한 고분자 초박막의 합성

  • 신재섭 (충북대학교 자연과학대학 화학과)
  • Received : 1996.08.13
  • Accepted : 1996.11.21
  • Published : 1996.12.10

Abstract

Cholesterol-containing surfactant was synthesized, and it was sonicated with monomer in water to form a vesicle solution. This vesicle solution was dried to construct a membrane which had a molecular multilayer structure. Using UV irradiation the monomer in this membrane were polymerized, and then surfactant was extracted by organic solvent. Using a X-ray diffractometer, the thickness of one layer and the regularity of the multilayer were measured. And scanning electron microscopy was conducted for fractured polymer film.

Keywords

Acknowledgement

Supported by : 한국과학재단

References

  1. Acc. Chem. Res. v.13 J. H. Fendler
  2. Membrane Mimetic Chemistry J. H. Fendler
  3. J. Am. Chem. Soc. v.103 M. S. Tunuli;J. H. Fendler
  4. J. Am. Chem. Soc. v.106 Y. M. Tricot;J. H. Fendler
  5. J. Chem. Soc., Chem. Commun. R. A. Moss;J. S. Shin
  6. J. Am. Chem. Soc. v.109 R. A. Moss;S. Bhattacharya;P. Scrimin;S. Swarup
  7. J. Am. Chem. Soc. v.114 R. A. Moss;Y. Okumura
  8. Polymer(Korea) v.15 I. Cho;J. S. Shin
  9. J. Kor. Ind. Eng. Chem. v.2 J. S. Shin
  10. J. Kor. Ind. Eng. Chem. v.3 D. H. Bae;K. S. Kim;J. S. Shin
  11. Macromolecules v.17 I. Cho;K. C. Chung
  12. Macromolecules v.21 I. Cho;K. C. Chung
  13. Chem. Lett. I. Cho;J. G. Park
  14. Polymer Bulletin v.24 I. Cho;Y. W. Kim
  15. J. Kor. Ind. Eng. Chem. v.3 I. Cho;S. H. Kim;J. S. Shin
  16. Polyer(Korea) v.18 I. Cho;S. J. Jeong;J. S. Shin
  17. Polyer(Korea) v.19 J. S. Shin
  18. Chemworld v.33 H. Lee
  19. Chemworld v.34 J. W. Park
  20. Polymer Sci. Tech. v.5 H. Lee
  21. Chem. Lett. N. Nakashima;R. Ando;T. Kunitake