Synthesis of 1,4-Bis(1'-alkyl-2',3',4',5'-tetraphenyl-1'-silacyclopentadienyl)benzenes

1,4-Bis(silyl)benzene의 고리화반응에 의한 1,4-Bis(1'-alkyl-2',3',4',5'-tetraphenyl-1'-silacyclopentadienyl)benzenes 리간드의 합성

  • 공영건 (경기대학교 이과대학 화학과) ;
  • 안영만 (경기대학교 이과대학 화학과)
  • Published : 19970200

Abstract

The 1,4-bis(alkyldichlorosilyl)benzene was synthesized to be a precursor of the bis(silacyclopentadienyl) aromatic system. The cyclization reaction of the precursor with 1,4-dilithio-1,2,3,4-tetraphenyl-1,3-butadiene produced the 1,4-bis(1'-alkyl-2',3',4',5'-tetraphenyl-1'-silacyclopentadienyl)benzene as the ligand of organotransition metal compound and the precursor of the stable silacyclopentadienyl anion.

Keywords

References

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