Analysis of Nitrophenols Using Liquid Chromatography/Atmospheric Pressure Chemical Ionization Mass Spectrometry

액체 크로카토그래피-대기압화학이온화법 질량분석기를 이용한 nitrophenol류의 분석

  • 홍종기 (기초과학지원연구소 질량분석그룹) ;
  • 유종신 (기초과학지원연구소 질량분석그룹) ;
  • 김강진 (고려대학교 화학과)
  • Received : 1996.08.31
  • Published : 1997.02.25

Abstract

Nitrophenols are a group of important priority pollutants classified by the US Environmental Protection Agency. Reverse-phase liquid chromatographic method combined with mass spectromethy employing atmospheric pressure chemical ionization(APCI) interface is utilized to determine a mixture of nitrophenols in water matrix without any pretreatment. The sensitivity and selectivity for the identification of different kind of nitrophenols is enhanced by the use of selected ion monitoring and cone voltage fragmentation. The fragmentation patterns of nitrophenols are compared with those obtained from the collision induced dissociation(CID) MS/MS technique.

Keywords

nitrophellols;LC/MS;APCI;cone voltage fragmentation

Acknowledgement

Supported by : Basic Science Research