Synthesis and Analytical Application of Piperidine Dithiocarbamate Complex of Copper(II)

피페리딘 디티오카바메이트의 구리(II)의 착물합성과 분석적 응용

  • Received : 1998.08.21
  • Published : 1999.02.25

Abstract

Copper(II) complex of piperidine dithiocarbamate (Pipdtc) was synthesized from the reaction of Cu(II) and piperidine dithiocarbamate. The possible structure of the complex was proposed on the basis of elemental analysis, molar conductivity, infrared spectroscopy, electronic absorption spectroscopy, and $^{13}C-NMR$ studies. The extraction of copper(II)-Pipdtc complex by carbon tetrachloride can be achieved in the pH range of 6.0~10. The solution of copper(II) with piperidine dithiocarbamate was bey Beer's law in the concentration up to ${\sim}8.0{\times}10^{-5}M$ at pH 9.0.

Keywords

piperidine dithiocarbamate complex;$^{13}C-NMR$;$CCl_4$ extraction

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Acknowledgement

Supported by : 대구대학교