Adsorption and Separation of Ag(I) Using a Merrifield Resin Bound NTOE, NDOE in Aqueous Solution

수용액에서 NTOE, NDOE가 결합된 Merrifield 수지를 이용한 Ag(I)의 흡착 및 분리 특성

  • Lee, Cheal-Gyu (Department of Environmental Engineering, Chongju University) ;
  • Kim, Hae Joong (Department of Chemistry, Chungbuk National University)
  • Received : 1998.12.05
  • Published : 1999.04.25

Abstract

The adsorption and separation behaviors of transition metal ions using a merrifield resin bound 1,12-diaza-3,4:9,10-dibenzo-5,8-dioxacyclopentadecane (NTOE) and 1,12,15-triaza-3,4:9,10-dibenzo-5,8-dioxacycloheptadecane(NDOE) were investigated in aqueous solution. The orders of adsorption degree(E) and distribution ratio(D) of transition metal ions were Cu(II)$t_R$) of metal ions were affected by adsorption degree(E) and distribution ratio(D). This results showed good separation efficiency of Ag(I) from mixed metal solution.

Keywords

merrifield resin bound NTOE and NDOE;adsorption degree;distribution ratio;hydration free energy of transition metal ions

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