Variable Layer Distance of Intercalates of Dodecanesulfonate in Hydrated Cobalt Compound

수화된 코발트에 도데칸술폰이 층상 삽입된 화합물의 가변 층 거리에 대한 연구

  • Huh, Y.D. (Department of Chemistry, Dankook University) ;
  • Jun, T.H. (Department of Chemistry, Dankook University) ;
  • Park, Y.J. (Korea Atomic Energy Research Institute)
  • 허영덕 (단국대학교 자연과학부 화학전공) ;
  • 전태현 (단국대학교 자연과학부 화학전공) ;
  • 박용준 (한국원자력연구소)
  • Received : 1999.09.03
  • Published : 2000.02.25

Abstract

The intercalated compound of dodecanesulfonate into hydrated cobalt was synthesized. The compound shows a layered structure as determined by high temperature X-ray diffraction. The layer distance of the product is increased from $19.1{\AA}$ to $34.7{\AA}$ by increasing the temperature from $30^{\circ}C$ to $200^{\circ}C$. We can control the layer distance by varying the temperature which is accomplished by changing from the monolayer to the bilayer structure of the intercalated dodecanesulfonate.

Keywords

high temperature X-ray diffraction;intercalation;layered structure

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