Synthesis and Characterization of Intercalation Compounds of Alkylsulfonate into Hydrated and Dehydrated Zinc

수화된 아연과 탈수된 아연에 알킬술폰이 층간 삽입된 화합물의 합성과 구조

  • 허영덕 (단국대학교 자연과학부 화학전공) ;
  • 박성훈 (고려대학교 이과대학 화학전공) ;
  • 전태현 (단국대학교 자연과학부 화학전공) ;
  • 박용준 (한국원자력 연구소 원자력화학 연구팀) ;
  • 박양순 (한국원자력 연구소 원자력화학 연구팀)
  • Received : 2000.04.09
  • Published : 2000.06.25

Abstract

The intercalated compounds of alkylsulfonate into hydrated and dehydrated zinc were synthesized. From the XRD, FT-IR, TGA, elemental analysis data, and the molecular size, the orientation of the intercalated alkylsulfonates was determined. For the hydrated compounds, alkylsulfonates were intercalated into hexaqua zinc layer with the bilayer structure of $32.9^{\circ}$ angle of inclination. For the dehydrated compounds, alkylsulfonates were directly bonded to zinc ion with the bilayer structure of $51.4^{\circ}$ angle of inclination.

Keywords

Alkylsulfonate;Intercalation;Layered structure

References

  1. Phys. Rev. A v.26 R. Kind;R. Blinc;H. Arend;P. Muralt;J. Slak;G. Chapuis;K. J. Schenk;B. Zeks
  2. Inorg. Chim. Acta v.201 E. J. Kosnic;E. L. McClymont;R. A. Hodder;P. J. Squattrito
  3. J. Am. Chem. Soc. v.119 S. H. Tolbert;P. S. Sieger;G. D. Stucky;S. M. J. Aubin;C. C. Wu;D. N. Hendrickson
  4. 화학교육 v.21 최종인;이명진;김범모;오원석
  5. Inorg. Chem. v.29 M. Meyn;K. Beneke;G. Lagaly
  6. J. Phys. Chem. v.88 L. Ricard;M. Rey-Lafaon;C. Biran
  7. J. Mater. Res. v.13 H. Morioka;H. Tagaya;M. Karasu;J. I. Kadokawa;K. Chiba
  8. Chem. Phys. Lett. v.226 E. Kanekazi;K. Kinugawa;Y. Ishikawa
  9. Solid State Ionics v.45 T. Sato;A. Okuwaki
  10. New J. Chem. S. P. Newmann;W. Jones
  11. Chem. Rev. v.95 M. Ogawa;K. Kuroda
  12. Anal. Sci. & Tech. v.6 W. C. Oh;M. K. Kim;Y. S. Ko
  13. Inorg. Chem. v.27 M. A. Drezdon
  14. J. Phys. Chem. v.92 K. J. Schenk;G. Chapuis
  15. Inorg. Chim. Acta v.258 B. J. Gunderman;I. D. Kabell;P. J. Squattrito;S. N. Dubey
  16. 70th ed. Handbook of Chemistry and Physics R. C. Weast
  17. J. Phys. Chem. Solid v.54 J. K. Kang;J. H. Choy;M. Rey-Lafaon