Analysis for 16 Polynuclear Aromatic Hydrocarbons (PAH) in Sewage Sludge and Soil

하수슬러지와 토양 중 다핵방향족 탄화수소의 정량

  • Kim, Jong-Hun (Dept. of Environ., Eng. & Sci. Jeonju University)
  • 김종훈 (전주대학교 응용과학부 환경공학전공)
  • Received : 2000.01.19
  • Published : 2000.06.25

Abstract

The polycyclic aromatic hydrocarbon (PAH) content in sewage sludge and in farm soils were determined by gas chromatography linked to mass spectrometry (GC/MS) with use 2-ethylantracene as internal standards. Twelve PAH were identified in both sludges with naphthalene ($0.78{\mu}g/g$) being the most predominant in industrial sludge and pyrene ($0.26{\mu}g/g$) in municipal sludge. The total PAR content in industrial sludge and in municipal sludge were $1.74{\mu}g/g$ and $1.19{\mu}g/g$ respectively. PAH were contained in paddy soils and the concentration were very low in the range of $0.01-0.04{\mu}g/g$. The total PAH content in industrial and in municipal sludge were about 9.2 times and 6.3 times greater than in paddy soils ($0.19{\mu}g/g$).

Keywords

16 PAH;sewage sludge;soils;GCIMS-SIM

References

  1. J. Chromatog. v.498 V. A. Gerasimenko;V. M. Navach
  2. Anal. Chem. v.66 V. L. Avila;R. Young;W. F. Beckert
  3. Anal. Sci. & Tech.(Korea) v.12 no.4 H. Choi;T. Kim
  4. Anal. Chem. v.68 M. D. David;J. N. Seiber
  5. Intern. J. Environ. Anal. Chem. v.62 R. Hartmann
  6. An improved HPLC method for polynuclear aromatic hydrocarbons. International Lambate D. W. Dong
  7. Environ. Sci. Technol. v.30 S. K. Lotfabad;M. A. Pickard;M. R. Gray
  8. J. Environ. Qual. v.21 S. R. Wild;K. C. Jones
  9. Soil Sci. Soc. Am. J. v.46 G. Sposito;L. J. Lund;A. S. Chang
  10. Anal. Chem. v.66 S. Reindl;F. Hofler
  11. J. Kor. Soc. Soil Sci. Fert. v.28 no.3 S. H. Yoo;J. Y. Lee;K. H. Kim
  12. Water Manegement & Research v.12 S. R. Wild;K. C. Jones
  13. Environmental endocrine disruptors, A Hand book of property data L. H. Keith
  14. J. Environ. Qual. v.12 N. T. Edwards
  15. The Science of the Total Environment v.101 S. R. Wild;J. P. Obbard;C. I. Munn;M. L. Berrow;K. C. Jones
  16. Land application of sludge A. L. Page;T. G. Logan;J. A. Ryan
  17. Toxicol. Ind. Health. v.6 J. J. Freeman;R. H. Mckee;R. D. Phillips
  18. Environ. Sci. Technol. v.24 S. R. Wild;K. S. Waterhouse;S. P. McGrath;K. C. Jones
  19. Canadian Journal of Biochemistry and Physiology v.37 E. G. Bligh;W. J. Dyer
  20. Nature v.370 no.7 S. L. Simonich;R. A. Hites
  21. Analytica Chimica Acta. v.237 W. Auer;H. Malissa
  22. PgD/MSc, Instrumental Analytical Chemistry(Pt/t) Polynuclear aromatic hydrocatbons, Environmental sources and current methods of analysis G. Sim
  23. Chemosphere v.28 A. Eschenbach;M. Kastner;R. Bierl;G. Schaefer;B. Mahro
  24. Appl. Spectrosc. v.43 J. W. Childer;N. K. Wilson;R. K. Barbour
  25. Analyst v.212 J. R. Dean
  26. Environmental Pollution v.76 S. R. Wild;M. L. Berrow;S. P. McGrath;K. C. Jones
  27. Environmental Pollution v.88 S. R. Wild;K. C. Jones
  28. Analyst. v.120 Y. Yang;W. Bauman
  29. Anal. Sci. & Technol. (Korea) v.12 J. H. Kim
  30. Environmental Toxicology and Chemistry v.12 S. R. Wild;K. C. Jones