DOI QR코드

DOI QR Code

Self-Assembly of Three-Dimensional Copper(II) Macrocyclic Complex with 2,5-Pyridinedicarboxylate Linked by Hydrogen Bond

수소 결합에 의한 삼차원의 Copper(II) 거대고리 착물과 2,5-Pyridinedicarboxylate와의 자기조립

  • Ki-Young Choi (Department of Chemistry Education, Kongju National University) ;
  • Haiil Ryu (Department of Chemistry Education, Kongju National University) ;
  • Yong-Son Kim (Department of Chemistry Education, Kongju National University)
  • 최기영 (공주대학교 사범대학 화학교육과) ;
  • 류해일 (공주대학교 사범대학 화학교육과) ;
  • 김용선 (공주대학교 사범대학 화학교육과)
  • Published : 2003.04.20

Abstract

The reaction of $[Cu(L)]Cl_2{\cdot}H_2O(L=3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,0^{1.18},0^{7.12}]docosane)$ with 2,5-pyridinedicarboxylate(pdc) led to the formation of $[Cu(L)(H_2O)](pdc){\cdot}6H_2O(1)$. The structure was characterized by X-ray crystallography and spectroscopic method. The coordination geometry around the copper atom is a distorted square-pyramid with four secondary amines of the macrocycle occupying the basal sites and a water molecule at the axial position. Intermolecular hydrogen bonds in 1 form a three-dimensional molecular network.

Keywords

Crystal Structure;Copper(II) Complex;2,5-Pyridinedicarboxylate;Three-Dimensional Chain

References

  1. Claessens, C. G.; Stoddart, J. F. J. Phys. Org. Chem.1997, 10, 254. https://doi.org/10.1002/(SICI)1099-1395(199705)10:5<254::AID-POC875>3.0.CO;2-3
  2. Subramanian, S.; Zaworotko, M. J. Coord. Chem. Rev.1994, 137, 357. https://doi.org/10.1002/(SICI)1521-3773(19990517)38:10<1405::AID-ANIE1405>3.0.CO;2-H
  3. Aaker y, C. B. Acta Crystallogr. 1997, B53, 569. https://doi.org/10.1021/ic980243g
  4. Videnova-Adrabi?ka, V. J. Mol. Struct. 1996, 374, 199. https://doi.org/10.1016/0022-2860(95)08975-6
  5. Desiraju, G. R. Chem. Commun. 1997, 1475. https://doi.org/10.1016/S1387-7003(99)00164-1
  6. Clegg, R. S.; Hutchison, J. E. J. Am. Chem. Soc. 1999, 121, 5319. https://doi.org/10.1021/ja9901011
  7. Burrows, A. D.; Mingos, D. M. P.; White, A. J. P.; Williams, D. J. J. Chem. Soc., Chem. Commun. 1996, 97.
  8. Goodson, P. A.; Glerup, J.; Hodgson, D. J.; Michelsen, K.; Rychlewska, U. Inorg. Chem. 1994, 33, 359. https://doi.org/10.1021/ic00080a027
  9. Cirujeda, J.; Mas, M.; Molins, E.; De Panthou, F. L.; Laugier, J.; Park, J. C.; Paulsen, C.; Ray, C.; Rovira, C.; Veciana, J. J. Chem. Soc., Chem. Commun. 1995, 709.
  10. Choi, H. J.; Lee, T. S.; Suh, M. P. Angew, Chem. Int. Ed. 1999, 38, 1405. https://doi.org/10.1023/A:1022894318159
  11. Bernhardt, P. V.; Hayes, E. J. Inorg. Chem. 1998, 37, 4214. https://doi.org/10.1021/ic980243g
  12. Bernhardt, P. V. Inorg. Chem. 1999, 38, 3483. https://doi.org/10.1016/0010-8545(94)03008-E
  13. Choi, K.-Y.; Suh, I.-H.; Hong, C. P. Inorg. Chem. Commu. 1999, 2, 604. https://doi.org/10.1016/S1387-7003(99)00164-1
  14. Kang, S.-G.; Kweon, J. K.; Jung, S. K. Bull. Korean Chem. Soc. 1991, 12, 483. https://doi.org/10.1021/ja00749a020
  15. Choi, K.-Y.; Kim, J. C.; Hensen, W. P.; Suh, I.-H.; Choi, S.-S. Acta Crystallogr. 1997, C52, 2166.
  16. Sheldrick, G. M. Acta Crystallogr. 1990, A46, 467. https://doi.org/10.1016/0022-2860(95)08975-6
  17. Sheldrick, G. M. SHELXL 97, Program for the Refinement of Crystal Structures; University of G ttingen: Germany, 1997.
  18. Choi, K.-Y. J. Chem. Crystallogr. 1998, 28, 875. https://doi.org/10.1021/ja9901011
  19. Choi, K.-Y.; Kim, M.-J.; Kim, D.-S.; Kim, Y.-S.; Kim, J.-H.; Ryu, H.; Lim, Y.-M.; Kang, S.-G.; Shin, U.-S.; Lee, K.-C.; Hong, C.-P. Bull. Korean Chem. Soc. 2002, 23, 1321. https://doi.org/10.5012/bkcs.2002.23.9.1321
  20. Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, 4th ed.; John Wiley and Sons: New York, 1986. https://doi.org/10.1021/ic00080a027
  21. Nielson, D. O.; Larsen, M. L. Willett, R. D.; Legg, J. I. J. Am. Chem. Soc. 1971, 93, 5079. https://doi.org/10.1021/ja00749a020

Cited by

  1. Synthesis, crystal structure, spectroscopic and thermal characterization of (Hampy)2[Ni(pydc)2(H2O)2] · 2 H2O vol.224, pp.4, 2009, https://doi.org/10.1524/zkri.2009.1112