Self-Assembly of Three-Dimensional Copper(II) Macrocyclic Complex with 2,5-Pyridinedicarboxylate Linked by Hydrogen Bond

수소 결합에 의한 삼차원의 Copper(II) 거대고리 착물과 2,5-Pyridinedicarboxylate와의 자기조립

  • Ki-Young Choi (Department of Chemistry Education, Kongju National University) ;
  • Haiil Ryu (Department of Chemistry Education, Kongju National University) ;
  • Yong-Son Kim (Department of Chemistry Education, Kongju National University)
  • 최기영 (공주대학교 사범대학 화학교육과) ;
  • 류해일 (공주대학교 사범대학 화학교육과) ;
  • 김용선 (공주대학교 사범대학 화학교육과)
  • Published : 2003.04.20


The reaction of $[Cu(L)]Cl_2{\cdot}H_2O(L=3,14-dimethyl-2,6,13,17-tetraazatricyclo[14,4,0^{1.18},0^{7.12}]docosane)$ with 2,5-pyridinedicarboxylate(pdc) led to the formation of $[Cu(L)(H_2O)](pdc){\cdot}6H_2O(1)$. The structure was characterized by X-ray crystallography and spectroscopic method. The coordination geometry around the copper atom is a distorted square-pyramid with four secondary amines of the macrocycle occupying the basal sites and a water molecule at the axial position. Intermolecular hydrogen bonds in 1 form a three-dimensional molecular network.


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