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Dimeric Silver(I) Complex: Bis(dipropyldithiophosphato) bis(1,10-phenanthroline) Disilver(I); Dimeric Silver(I) Complex: Bis(dipropyldithiophosphato) bis(1,10-phenanthroline) Disilver(I);Ag2[Phen]2[S2P(OPr)2]2

은(I)화합물:비스(디프로필디싸이오포스페이토)비스(1,10-펜안트로린)이온(I);Ag2[Phen]2[S2P(OPr)2]2

  • Fang Fang Jian (New Materials & Function Coordination Chemistry Laboratiry, Qingdao University of Science and Technology) ;
  • Hai Lian Xiao (New Materials & Function Coordination Chemistry Laboratiry, Qingdao University of Science and Technology) ;
  • Huan Xiang Wang (New Materials & Function Coordination Chemistry Laboratiry, Qingdao University of Science and Technology) ;
  • Kui Jiao (New Materials & Function Coordination Chemistry Laboratiry, Qingdao University of Science and Technology)
  • Published : 2003.02.20

Abstract

The dinuclear $Ag_2[Phen]_2[S_2P(OPr)_2]_2$(phen=1,10-phenanthroline; Pr=propyl), was prepared by the reaction of bis(dipropyldithiophosphato) silver(I) complex with 1,10-phenanthroline ligand, and its structure was determined by X-ray crystallography. The two dipropyldithiophosphato ligands each bridge two silver atoms to form an eight-membered $Ag_2S_4P_2$ ring, while the 1,10-phenanthroline molecule coordinates to a silver atom to complete the local tetrahedral geometry for the metal ion. The Ag-S bond distances are 2.559(1) and 2.567(1)${\AA}$, and the Ag-N bond distances are 2.366(3) and 2.471(3)${\AA}$.

Keywords

Phen Ligand;Crystal Structure;Dimeric Silver(I);Dithiophosphate

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