Crystal Structure of Antimony-sorbed Indium-exchanged Zeolite A

인디움 제올라이트 A의 안티몬 흡착과 결정구조

  • Lim, Woo Taik (Department of Applied Chemistry, Andong National University) ;
  • Lee, Hyun Su (Department of Applied Chemistry, Andong National University) ;
  • Heo, Nam Ho (Department of Industrial Chemistry, Kyungpook National University)
  • 임우택 (안동대학교 자연과학대학 응용화학과) ;
  • 이현수 (안동대학교 자연과학대학 응용화학과) ;
  • 허남호 (경북대학교 공과대학 공업화학과)
  • Received : 2002.08.07
  • Accepted : 2003.09.16
  • Published : 2003.10.25

Abstract

A single crystal of fully indium-exchanged zeolite A (In-A) was brought into contact with antimony in a fine Pyrex capillary at $350^{\circ}C$ for 6 days. The reaction was monitored by electron-probe X-ray microanalysis (EPXMA). The crystal structure of antimony-sorbed indium-exchanged zeolite A has been determined by single-crystal X-ray diffraction techniques at $21^{\circ}C$ in the cubic space group Pm ${\bar{3}}m$. The crystal structure of $In_8Si_{12}Al_{12}O_{48}{\cdot}(In)_{1.35}(Sb)_{0.7}$ ($a=12.111(2){{\AA}}$, $R_1=0.071$, and $R_2=0.067$) has 8 indium cations, 1.35 indium atoms, and 0.7 antimony atoms per unit cell. Unit cell 1 ($In_8-A{\cdot}In$, 65% of unit cells) contain the $(In_5)^{8+}$ cluster. In unit cell 2 ($In_8-A{\cdot}(In)_2(Sb)_2$, 35% of unit cells), two $(In_3)^{2+}$ cluster and one $(In_3Sb_2)^{7+}$ cluster are found in the large cavity.

Keywords

Zeolite A;Indium;Antimony;EPXMA;Single-crystal X-ray diffraction

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