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Effect of n-Butanol on the Micellization of DBS/Brij 35 Mixed Surfactant Systems

DBS/Brij 35 혼합계면활성제의 미셀화에 미치는 n-부탄올 효과

  • Published : 2006.10.20

Abstract

The critical micelle concentration (CMC) and the counterion binding constant (B) in a mixed micellar state of the sodium dodecylbenzenesulfonate (DBS) with the polyoxyethylene(23) lauryl ether (Brij 35) at 25oC in water and aqueous solutions of n-butanol (0.1M, 0.2M, and 0.3M) were determined as a function of a1 (the overall mole fraction of DBS) by the use of electric conductivity method and surface tensiometer method. Various thermodynamic parameters (Xi, i, Ci, aiM, , and Hmix) were calculated by means of the equations derived from the nonideal mixed micellar model. The effect of n-butanol on the micellization of the DBS/Brij 35 mixtures has been also studied by analyzing the measured and calculated thermodynamic parameters.

Keywords

DBS;Brij 35;Critical Micelle Concentration;Counter Ion Binding Constant;Non Ideal Mixed Micellar Model

References

  1. Gerber, S.; Garamas, V. M.; Milkereit, G.; Vill, V. Langmuir 2005, 21, 6707 https://doi.org/10.1021/la050439a
  2. Kim, Y. C.; Lee, B. H. J. Kor. Chem. Soc. 2005, 49, 435 https://doi.org/10.5012/jkcs.2005.49.5.435
  3. Shanks, P. C.; Franses, E. I. J. Phys. Chem, 1992, 96, 1794 https://doi.org/10.1021/j100183a055
  4. Park, I. J.; Lee, B. H. J. Kor. Chem. Soc. 2006, 50, 190 https://doi.org/10.5012/jkcs.2006.50.3.190
  5. Park, I. J.; Lee, B. H. J. Kor. Univ. of Tech. & Edu. 2006, 12, 259
  6. Holland, P. M.; Rubingh, D. N. J. Phys. Chem. 1983, 87, 1984 https://doi.org/10.1021/j100234a030
  7. Myers, D. In Surfactants Science and Technology; VCH Publishers Inc.: New York, U.S.A., 1998
  8. Muto, Y.; Asada, M.; Takasawa, A.; Esumi, K.; and Meguro, K. J. Colloid Interface Sci. 1988, 124, 632 https://doi.org/10.1016/0021-9797(88)90200-7
  9. Treiner, C.; Nortz, M.; Vaution, C.; Puisieux, F. J. Colloid Interface Sci 1988, 125, 261 https://doi.org/10.1016/0021-9797(88)90074-4
  10. Clint, J. H. In Surfactant aggregation, Chapman and Hall: New York, U.S.A., 1992; p.130
  11. Kumbhakar, M.; Goel, T.; Mukerjee, T.; Pal, H. J. Phys. Chem. B 2005, 109, 14168 https://doi.org/10.1021/jp0520291
  12. Hassan, P. A.; Bhagwat, S. S.; Manohar, C. Langmuir, 1995, 11, 470 https://doi.org/10.1021/la00002a017
  13. Gorski, N.; Gradzielski, M.; Hoffmann, H. Langmuir, 1994, 10, 2594 https://doi.org/10.1021/la00020a018
  14. Warr, G. G.; Greiser, F.; Healy, T. W. J. Phys. Chem., 1993, 87, 1220
  15. Holland, P. M. In Mixed Surfactant System; Holland, P. M.; Rubingh, D. N. Ed.; ACS Symposium Series, American Chemical Society: Washington DC, U.S.A., 1992; p.31
  16. Bastiat, G.; Gras, B.; Khoukh, A.; Francois, J. Langmuir 2004, 20, 5759 https://doi.org/10.1021/la049890c
  17. Kim, H. U.; Lee, J. K.; Lim, K. H. J. Korean Ind. Eng. Chem. 2005, 16, 231
  18. Esumi, K.; Ogawa, M. Langmuir, 1993, 9, 358 https://doi.org/10.1021/la00025a067
  19. Zana, R.; Picot, C.; Duplessix, R. J. Colloid Interface Sci. 1983, 93, 43 https://doi.org/10.1016/0021-9797(83)90382-X
  20. Penfold, J.; Tucker, I.; Thomas, R. K.; Staples, E.; Schuermann, R. J. Phys. Chem. B 2005, 109, 10770 https://doi.org/10.1021/jp052426b
  21. Park, J. W.; Chung, M. A.; Choi, K. M. Bull. Korean Chem., Soc. 1989, 10, 437
  22. Sharma, K. S.; Patil, S. R.; Rakshit, A. K. J. Phys. Chem. B. 2004, 108, 12804 https://doi.org/10.1021/jp048294o

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  2. Comparative Study on the Mixed Micellizations of Anionic Surfactant (DBS) with Nonionic Surfactnats (Brij 30 and Brij 35) vol.53, pp.5, 2009, https://doi.org/10.5012/jkcs.2009.53.5.491