Separation properties of 209 PCB congeners on capillary columns and identification of PCBs congeners in aroclor standards for source identification

오염원 해석을 위한 폴리염화비페닐류(PCBs) 209 이성체의 컬럼별 분리 특성과 Aroclor 표준품의 이성체 확인

  • Received : 2006.07.12
  • Accepted : 2006.08.02
  • Published : 2006.08.28


This study was performed to search for useful separation properties and elution orders of three GC columns (DB-1, DB-5MS, SPB-Octyl) for 209 PCBs congeners using M-1668A-0.01X-SET of the AccuStandard Inc.. In addition, to confirm the quantitative peak in peak pattern method, the IUPAC Nos. of PCBs congener peaks were identified with 4 Aroclor standards (Aroclor-1242, 1248, 1254 and 1260). The separation property of dioxin-like PCBs congeners by four columns (DB-1, DB-5MS, SP-2331 and SPB-Octyl) was excellent in SP-2331. DB-1 and SPB-Octyl columns are necessary to use with a column of other types.


PCBs;GC column;separation property;Aroclor


  1. Hirai, Y., Congener情報を用いた大中Dioxin-like PCB の生源にする究, 일본 요코하마국립대학, 석사학위논 문, 2002
  2. Vetter, W., Luckas, B., and Buijten, J., J. Chromatogr. A, 799, 249-258(1998)
  3. Masuzaki, Y., and Matsumura, T., 제12회 일본 환경 화학토론회 강연요지집, 688-689(2003)
  4. Harju, M.T., Haglund, P., and Naikwadi, K.P., Organohalogen compounds, 35, 111-114(1998)
  5. 국립환경연구원, '절연유 중 폴리염화비페닐류 (PCBs) 세부분석지침', 2004
  6. 김종국, 박진수, 김경심, 이근희, 김신조, 한국분석과학회지, 15(1), 43-53(2002)
  7. McFarland, V.A. and Clarke, J.U, Environ. Health Perspect, 81, 225-239(1989)
  8. U.S. EPA,
  9. 김경수, 김형섭, 송병주, 정미정, 김종국, 박석운, 신 선경, 한국분석과학회지, 18(3), 232-240(2005)
  10. 홍종기, 양정수, 신정화, 안윤경, 이대운, 한국분석과학회지, 17(2), 184-191(2004)
  11. Frame, G.M., Cochran, J.W., and Boewadt, S.S, J. High Res. Chromatogr., 19, 657-668(1996)
  12. 여현구, 최민규, 천만영, 선우영, 대한환경공학회지, 24(5), 800-813(2002)
  13. 국립환경과학원, PCBs 함유 제품 및 폐기물 중의 PCBs 분석방법 개발, 2005
  14. Mikael, T.H., Haglund, P., and Naikwadi, K.P., Organohalogen compounds, 35, 111-114(1998)
  15. U.S. EPA, Method 1668 Revision A: Chlorinated Biphenyl Congeners in Water, Soil, Sediment, and Tissue by HRGC/HRMS, 1999
  16. Mimura, K., Ramura, M., Haraguchi, K., and Masuda, Y., 福岡誌, 90(5), 192-201(1999)
  17. Kobayashi, N., 東京流域の環境水中におけるダイオキ シン類汚染の態把握とモデルを用いた濃度予測, 일본 요코하마국립대학, 박사학위논문, 2004


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