Separation properties of 209 PCB congeners on capillary columns and identification of PCBs congeners in aroclor standards for source identification

오염원 해석을 위한 폴리염화비페닐류(PCBs) 209 이성체의 컬럼별 분리 특성과 Aroclor 표준품의 이성체 확인

  • Received : 2006.07.12
  • Accepted : 2006.08.02
  • Published : 2006.08.28

Abstract

This study was performed to search for useful separation properties and elution orders of three GC columns (DB-1, DB-5MS, SPB-Octyl) for 209 PCBs congeners using M-1668A-0.01X-SET of the AccuStandard Inc.. In addition, to confirm the quantitative peak in peak pattern method, the IUPAC Nos. of PCBs congener peaks were identified with 4 Aroclor standards (Aroclor-1242, 1248, 1254 and 1260). The separation property of dioxin-like PCBs congeners by four columns (DB-1, DB-5MS, SP-2331 and SPB-Octyl) was excellent in SP-2331. DB-1 and SPB-Octyl columns are necessary to use with a column of other types.

Keywords

PCBs;GC column;separation property;Aroclor

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Acknowledgement

Supported by : 환경부