Analytic study on lead and cadmium in glass materials

유리소재의 Pb 및 Cd 분석에 관한 연구

  • Choi, Zel-Ho (General Test & Analysis Center, Korea Institute of Ceramic Eng. & Tech.) ;
  • Ko, Jae-Kwon (General Test & Analysis Center, Korea Institute of Ceramic Eng. & Tech.)
  • 최철호 (요업(세라믹)기술원 종합시험분석센터) ;
  • 고재권 (요업(세라믹)기술원 종합시험분석센터)
  • Received : 2006.10.24
  • Accepted : 2006.12.08
  • Published : 2007.02.28

Abstract

The determination method for the trace lead and cadmium in glass materials was developed by ICP-AES. The lead- and cadmium-DDTC chelates were formed by adding Na-DDTC (sodium diethyldithiocarbamate) as a chelating agent and extracted into MIBK (methyl-isobutyl ketone). Direct measuring of the trace lead and cadmium in glass was not possible because of the interferences of matrix elements as Na, Si, Mg and Ca of glasses unless solvent extraction of lead and cadmium was applied. This procedure was confirmed to be valid quantitative method of Pb and Cd analysis in glass did not influence of sample matrix, by applying it procedure to artifact sample and NIST SRM 1412.

Keywords

Lead;Cadmium;Na-DDTC;solvent extraction;interferences of matrix elements

Acknowledgement

Supported by : 산업자원부

References

  1. J. Wang, T. Nakazako, K. Sakanishi, O. Yamada, H. Tao and I. Saito, Talanta, 68, 1584 (2006) https://doi.org/10.1016/j.talanta.2005.08.034
  2. J. Flanjak and A. Hodda, Anal. Chim. Acta, 72, 313 (1985). https://doi.org/10.1016/S0003-2670(01)82951-2
  3. V. Sandroni and C. M. M. Smith, Anal. Chim. Acta, 468, 335 (2002)
  4. EU, 'Directive 2000/53/EC of the European Parliament and of the Councile', 2000
  5. R. A. Sutherland and F. M. G. Taek, Advances in Envi-ronmental Research, 8, 37 (2003) https://doi.org/10.1016/S1093-0191(02)00144-2
  6. ASTM C 169-92
  7. P. J. Stratham, Anal. Chim. Acta, 169, 149 (1985)
  8. L. G. Danielsson, B. Magnusson, S. Westerlund and K. Zhang, Anal. Chim. Acta, 144, 183 (1982)
  9. 박용안, 요업학회지, 10(6), 515 (1995)
  10. T. Ishizuka, Y. Uwamino and A. Tange, Anal. Chim. Acta, 161, 285 (1984)
  11. K. J. Iroglic, Anal. Chim. Acta, 196, 23 (1987)
  12. J. A. C. Broekaert, T. Graule, H. Janett, G. Tolg and P. Tschopel, Fresenius Z. Anal. Chem., 322, 825 (1989)
  13. K. V. Krishnarnurty and M. M. Reddy, Anal. Chem., 49, 222 (1977)