Curie Temperature Transition According to Microstructure of Polymer Chain in Poly(VDF/TrFE/CTFE) Terpolymer

Poly(VDF/TrFE/CTFE) 3성분계 고분자의 배열구조에 따른 상전이 온도의 변화

  • Kim, Eun-Kyoung (Research Center for Biorefinery, Korea Research Institute of Chemical Technology) ;
  • Lee, Sang-Goo (Research Center for Biorefinery, Korea Research Institute of Chemical Technology) ;
  • Ha, Jong-Wook (Research Center for Biorefinery, Korea Research Institute of Chemical Technology) ;
  • Park, In-Jun (Research Center for Biorefinery, Korea Research Institute of Chemical Technology) ;
  • Lee, Soo-Bok (Research Center for Biorefinery, Korea Research Institute of Chemical Technology) ;
  • Park, Cheol-Min (Department of Matallurgical System Engineering, School of Advanced Materials Engineering, Yonsei University) ;
  • Kim, Young-Ho (Department of Fine Chemical Engineering & Chemistry, Chungnam National University)
  • 김은경 (한국화학연구원 바이오리파이너리센터) ;
  • 이상구 (한국화학연구원 바이오리파이너리센터) ;
  • 하종욱 (한국화학연구원 바이오리파이너리센터) ;
  • 박인준 (한국화학연구원 바이오리파이너리센터) ;
  • 이수복 (한국화학연구원 바이오리파이너리센터) ;
  • 박철민 (연세대학교 금속시스템공학과) ;
  • 김영호 (충남대학교 공업화학과)
  • Published : 2007.07.31

Abstract

In this study, terpolymer of vinylidene fluoride (VDF), trifluoroethylene (TrFE), and chlorotrifluoroethylene (CTFE) were prepared by suspension polymerization using di-tertiary-butyl peroxide (DTBP) as an initiator. The structural characteristics including microstructure and chain conformation of the polymers have been carefully elucidated as a function of the chemical composition using NMR, FT-IR. The intensity of absorption bands of the $\beta$-phase gradually decreases and the $\gamma$-phase increases with the increment of CTFE mol%. The analysis results of DSC shows that the Curie phase transition temperature ($T_c$) of the terpolymer gradually shifts to ambient temperature and trace becomes smaller and broader with the increment of CTFE mol%. Also, activation energies of the samples were calculated by Freeman-Carroll method.

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