Preparation of Self-Assembled of $\alpha$-D-Mannosyl Fullerene[$C_{60}$]-Gold Nanoparticle Films

자기조립법에 의한 $\alpha$-D-만노실 풀러렌[$C_{60}$]-금 나노입자 필름 제조

  • Published : 2008.12.31


$\alpha$-D-mannosyl fullerene[$C_{60}$]-functionalized gold nanoparticle films were selfassembled using the layer-by-layer method on the reactive of glass slides functionlized with 3-aminopropyltrimethoxysilane. The functionalized glass slides were alternately soaked in the solutions containing $\alpha$-D-mannosyl fullerene[$C_{60}$] and 4-aminothiophenoxide/hexanethiolate-protected gold nanoparticles. $\alpha$-D-mannosyl fullerene[$C_{60}$]-functionalized gold nanoparticle films have grown up to 5 layers depending on the immersion time. The self-assembled nanoparticle films were characterized using UV-vis spectroscopy showed that the surface plasmon band of gold at 530 nm gradually became more evident as successive layers were added to the films.


  1. Z. Yinghuai, "Application of Ultrasound Technique in the Synthesis of Methanofullerene Derivatives", J. Phys. Chem. Solids, 65, 349 (2004)
  2. W. B. Ko and K. N. Baek, "The Oxidation of Fullerenes $(C_{60},\;C_{70})$ with Various Oxidants under Ultrasonication", Phys. Solid State, 44, 424 (2002)
  3. W. B. Ko, Y. H. Park, and M. K. Jeong, "Preparation of a Water‐Soluble Fullerene $[C_{70}]$ under Ultrasonic Irradiation", Ultrasonics, 44, e367 (2006)
  4. F. Cataldo and D. Heymann, "Effects of Intense Ultrasound Treatment of $C_{60}]$ Solutions", Fullerene Sci.Technol., 7, 725 (1999)
  5. K. S. Suslick, "Ultrasound, Its Chemical, Physical and Biological Effect", ed. By K. S. Suslick, VCH publishers, Weinheim, 1989
  6. R. P. Andres, J. D. Bielifeld, J. I. Henderson, D. V. Janes, V. R. Kolagunta, C. P. Kubiak, W. J. Mahoney, and R. G. Osifchin, "Self- Assembly of a Two-Dimensional Superlattice of Molecularly Linked Metal Clusters", Science, 273, 1690 (1996)
  7. F. P. Zamborini, J. F. Hicks, and R. W. Murray, "Quantized Double Layer Charging of Nanoparticle Films Assembled /Using Carboxylate/($Cu^{2+}$ or $Zn^{2+}$)/ Carboxylate Bridges", J. Am. Soc., 122(18), 4514 (2000)
  8. J. Kolny, A. kornowski, and H. Weller, "Self- Organization of Cadmium Sulfide and Gold Nanoparticles by Electrostatic Interaction", Nano. Lett., 4, 361 (2002)
  9. S. Sun, S. Anders, H. F. Hammann, J. Thiele, J. EE. Baglin, T. Thomson, E. E. Fullerton, C. B. Murray, and B. D. Terris, "Polymer Mediated Self-Assembly of Magnetic Nanoparticles", J. Am. Chem. Soc., 124(12), 2884 (2002)
  10. Y. S. Shon and H. Choo, "[60]Fullerene-Linked Gold Nanoparticles: Synthesis and Layer-by- Layer Growth on a Solid Surface", Chem. Commun., 2560 (2002)
  11. F. Deng, Y. Yang, S. Hwang, Y. S. Shon, and S. Chen, "Fullerene-Functionalized Gold Nanoparticles: Electrochemical and Spectroscopic Properties", Anal. Chem., 76(20) 6102 (2004)
  12. M. R. Banks, J. I. G. Cadogan, I. Gosney, P. K. G. Hodgson, P. R. R. L.-Smith, J. R. A. Millar, J. A. Parkinson, D. W. H. Rankin and A. T. Taylor, "Aziridino[2, 3 : 1, 6][60]Fullerene: Isolation of the First Closed [5,6]-Bridged Fullerene Adduct", J. Chem. Soc. Chem. Commun., 887 (1995)
  13. A. Y. Chernyak, G. V. M. Sharma, L. O. Kononov, P. R. Krishna, A. B. Levinsky, N. K. Kochetkov, and A. V. R. Rao, "2-Azidoethyl Glycosides: Glycosides Potentially Useful for the Preparation of Neoglycoconjugates", Carbohydr. Res., 223, 303 (1992)
  14. H. Kato, A. Yashiro, A. Mizuno, Y. Nishida, K. Kobayashi, and H. Shinohara, "Syntheses and Biological Evaluations of $\alpha$-D-Mannosyl [60]Fullerenols", Bioorg. Med. Chem. Lett., 11, 293 (2001)