X-ray crystal structure of two-dimensional bimetallic host clathrate with 2-aminoethanol, [Cd{NH2CH2CH2OH}2Ni(CN)4]·3C6H5NH2·H2O

  • Kim, Chong-Hyeak (Center for Chemical Analysis, Korea Research Institute of Chemical Technology) ;
  • Moon, Hyoung-Sil (Center for Chemical Analysis, Korea Research Institute of Chemical Technology) ;
  • Lee, Sueg-Geun (Center for Chemical Analysis, Korea Research Institute of Chemical Technology)
  • Received : 2008.10.09
  • Accepted : 2008.11.03
  • Published : 2008.12.25

Abstract

A novel two-dimensional cadmium(II)-nickel(II) bimetallic host clathrate, $[Cd{NH_2CH_2CH_2OH}_2Ni(CN)_4]{\cdot}3C_6H_5NH_2{\cdot}H_2O$, 1, has been synthesized and structurally characterized by X-ray single crystallographic method. The clathrate 1 crystallizes in the monoclinic system, space group $P2_1/c$ with a = 14.370(3), b = 7.728(1), c = 28.172(4) ${\AA}$, ${\beta}=97.58(1)^{\circ}$, V = 3101.1(9) ${\AA}^3$, Z = 4. The host framework of the clathrate 1 is built of the cyanide bridges between octahedral Cd(II) atom and square planar Ni(II) atom. The octahedral Cd atoms ligated by two 2-aminoethanol molecules and four cyanide ligands bridged with square planar Ni atoms. The Ni atoms bridges to four Cd atoms via cyanides is made up of puckered quadrangles of composition $\{CdNi(CN)_2\}_2$, all edges are shared. This cyanide bridges form an infinite two-dimensional host networks stacking along b axis. 2-Aminoethanol ligands bond to Cd atom through N atom as a monodentate ligand in the axial position and four cyanides take an equatorial plane with all in trans-configurations. The aniline guest molecules and water molecules are located in between the host layer sheets, respectively.

Keywords

cadmium(II)-nickel(II) bimetallic clathrate;2-aminoethanol ligand;aniline guest;crystal structure

References

  1. A. Reichert, H. Ringsdorf, P. Schuhmacher, W. Baumeister and T. Scheybani, "Comprehensive Supramolecular Chemistry", Vol. 9, p. 313, Pergamon Press, Oxford, U.K., 1996
  2. J. Y. Ying, C. P. Mehnert and M. S. Wong, Angew. Chem. Int. Ed., 38, 56(1999) https://doi.org/10.1002/(SICI)1521-3773(19990115)38:1/2<56::AID-ANIE56>3.0.CO;2-E
  3. S. Noro, R. Kitaura, M. Kondo, S. Kitagawa, T. Ishii, H. Matsuzaka and M. Yamashita, J. Am. Chem. Soc., 124, 2568(2002) https://doi.org/10.1021/ja0113192
  4. C. H. Kim, S. G. Lee and I. H. Suh, Acta Cryst., C55, 1238(1999)
  5. S. S. Yun, Y. P. Kim and C. H. Kim, J. Coord. Chem., 56, 363(2003) https://doi.org/10.1080/0095897031000092421
  6. J. P. Costes, J. F. Serra, F. Dahan and J. P. Laurent, Inorg. Chem., 25, 2790(1986) https://doi.org/10.1021/ic00236a027
  7. G. M. Sheldrick, Acta Cryst., A46, 467 (1990)
  8. J. P. Costes, F. Dahan and J. P. Laurent, Inorg. Chem., 30, 1887(1991) https://doi.org/10.1021/ic00008a039
  9. T. Iwamoto, "Comprehensive Supramolecular Chemistry", Vol. 6, chap. 19, Pergamon Press, Oxford, U.K., 1996
  10. A. L. Balch, B. C. Noll and N. Safari, Inorg. Chem., 32, 2901(1993) https://doi.org/10.1021/ic00065a017
  11. K. Nakamoto, "Infrared and Raman Spectra of Inorganic and Coordination Compounds", Part B, John Wiley & Sons, New York, U.S.A., 1997
  12. S. S. Yun, Y. P. Kim and C. H. Kim, Acta Cryst., C55, 2026(1999)
  13. S. R. Batten and R. Robson, Angew. Chem. Int. Ed., 37, 1460(1998) https://doi.org/10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO;2-Z
  14. J. Kozisek, H. Paulus, M. Dankova and M. Hvastijova, Acta Cryst., C52, 3019(1996)
  15. H. Yuge and T. Iwamoto, J. Incl. Phenom., 14, 217 (1992) https://doi.org/10.1007/BF01045982
  16. Bruker, SHELXTL Structure Analysis Software Package, Bruker, Karlsruhe, Germany, 1998
  17. T. Iwamoto, "Inclusion Compounds", vol. 1, chap. 2, Academic Press, London, U.K., 1984
  18. T. Iwamoto, "Inclusion Compounds", vol. 5, chap. 6, Oxford Univ. Press, Oxford, U.K., 1991
  19. H. J. Chen, G. Yang and X. M. Chen, Acta Cryst., C55, 2012 (1999)
  20. L. Isaacs, D. N. Chin, N. Bowden, Y. Xia and G. M. Whitesides, "Supramolecular Materials and Technologies", p. 1, John Wiley & Sons, New York, U.S.A., 1999
  21. P. Bombicz, J. Madarasz, E. Forizs, and I. Foch, Polyhedron, 16, 3601(1997) https://doi.org/10.1016/S0277-5387(97)00104-6
  22. H. S. Moon, C. H. Kim and S. G. Lee, Acta Cryst., C56, 425(2000)
  23. S. S. Yun, H. S. Moon, C. H. Kim and S. G. Lee, J. Coord. Chem., 57, 17(2004) https://doi.org/10.1080/00958970310001641709
  24. H. S. Moon, C. H. Kim and S. G. Lee, Bull. Korean Chem. Soc., 21, 339(2000)
  25. Bruker, XSCANS Data Collection Software Package, Bruker, Karlsruhe, Germany, 1996
  26. S. S. Yun, H. S. Moon, C. H. Kim and S. G. Lee, J. Coord. Chem., 57, 321(2004) https://doi.org/10.1080/00958970410001671165