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Synthesis of Organic Dyes with Linkers Between 9,9-Dimethylfluorenyl Terminal and α-Cyanoacrylic Acid Anchor, Effect of the Linkers on UV-Vis Absorption Spectra, and Photovoltaic Properties in Dye-Sensitized Solar Cells

  • Lee, Min-Woo (Department of Chemistry, Sogang University) ;
  • Cha, Su-Bong (Department of Chemistry, Sogang University) ;
  • Yang, Su-Jin (Department of Chemistry, Sogang University) ;
  • Park, Se-Woong (Solar Cell Research Center, Korea Institute of Science and Technology(KIST)) ;
  • Kim, Kyung-Kon (Solar Cell Research Center, Korea Institute of Science and Technology(KIST)) ;
  • Park, Nam-Gyu (Solar Cell Research Center, Korea Institute of Science and Technology(KIST)) ;
  • Lee, Duck-Hyung (Department of Chemistry, Sogang University)
  • Published : 2009.10.20

Abstract

Six metal-free organic dyes having thiophene (1), benzene-thiophene (2), thiophene-benzene (3), thiophene-pyridine (4), thiophene-thiophene (5), and pyridine (6) linkers between 9,9-dimethylfluorenyl terminal group and $\alpha$-cyanoacrylic acid anchor were synthesized. Among them, organic dye 5 showed the longest ${\lambda}_{max}$ value (424 nm) in UV-Vis absorption spectrum, better incident monochromatic photon-to-current conversion efficiency (IPCE), highest short circuit photocurrent density ($J_{SC},\;9.33\;mA^2/cm^2$), and highest overall conversion efficiency ($\eta$, 3.91%).

Keywords

References

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