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Adsorption Characteristics of As(V) onto Cationic Surfactant-Modified Activated Carbon

  • Published : 2009.09.30

Abstract

Arsenic at abandoned mine sites has adversely affected human health in Korea. In this study, the feasibility of using cationic surfactant-modified activated carbon (MAC) to remove As(V) was evaluated in terms of adsorption kinetics, adsorption isotherms, and column experiments. The adsorption of As(V) onto MAC was satisfactorily simulated by the pseudo-second-order kinetics model and Langmuir isotherm model. In column experiments, the breakthrough point of AC was 28 bed volumes (BV), while that of MAC increased to 300 BV. The modification of AC using cationic surfactant increased the sorption rate and sorption capacity with regard to As(V). As a result, MAC is a promising adsorbent for treating As(V) in aqueous streams.

Keywords

Arsenic;Adsorption kinetics;Adsorption isotherm;Surfactant-modified activated carbon

References

  1. Concas, A., Ardau, C., Cristini, A., Zuddas, P., and Cao, G., “Mobility of heavy metals from tailings to stream waters in a mining activity contaminated site,” Chemosphere, 63, 244-253 (2006). https://doi.org/10.1016/j.chemosphere.2005.08.024
  2. Zaw, M. and Emett, M. T., “Arsenic removal from water using advanced oxidation processes,” Toxicol. Lett., 133, 113-118 (2002). https://doi.org/10.1016/S0378-4274(02)00081-4
  3. Chutia, P., Kato, S., Kojima, T., and Satokawa, S., “Adsorption of As(V) on surfactant-modified natural zeolite,” J. Hazard. Mater., 162, 204-211 (2009). https://doi.org/10.1016/j.jhazmat.2008.05.024
  4. Wu, Y., Ma, X., Feng, M., and Liu, M., “Behavior of chromium and arsenic on activated carbon,” J. Hazard. Mater., 159, 380-384 (2008). https://doi.org/10.1016/j.jhazmat.2008.02.059
  5. Ho, Y.-S., “Review of second-order models for adsorption systems,” J. Hazard. Mater., 136, 681-689 (2006). https://doi.org/10.1016/j.jhazmat.2005.12.043
  6. Azizian, S., “Kinetic model of sorption: a theoretical analysis,” J. Colloid Interf. Sci., 276, 47-52 (2004). https://doi.org/10.1016/j.jcis.2004.03.048
  7. Lee, C.-G., Chon, H.-T., and Jung, M.-C., “Heavy metal contamination in the vicinity of the Daduk Au-Ag-Pb-Zn mine in Korea,” Appl. Geochem., 16, 1377-1386 (2001). https://doi.org/10.1016/S0883-2927(01)00038-5
  8. Basar, C. A., Aydiner, C., Kara, S., and Keskinler, B., “Removal of CrO4 anions from waters using surfactant enhanced hybrid PAC/MF process,” Sep. Purif. Technol., 48, 270-280 (2006). https://doi.org/10.1016/j.seppur.2005.07.033
  9. Natale, F. D., Erto, A., Lancia, A., and Musmarra, D., “Experimental and modeling analysis of As(V) ions adsorption on granular activated carbon,” Water Res., 42, 2007-2016 (2008). https://doi.org/10.1016/j.watres.2007.12.008
  10. Kundu, S. and Gupta, A. K., “Adsorption characteristics of As(III) from aqueous solution on iron-oxide coated cement (IOCC),” J. Hazard. Mater., 142, 97-104 (2007). https://doi.org/10.1016/j.jhazmat.2006.07.059
  11. Bingol, A., Ucun, H., Bayhan, Y. K., Karagunduz, A., Cakici, A., and Keskinler, B., “Removal of chromate anions from aqueous stream by a cationic surfactant-modified yeast,” Bioresource Technol., 94, 245-249 (2004). https://doi.org/10.1016/j.biortech.2004.01.018
  12. Kim, H.-C., Park, S.-J., Lee, C.-G., Han, Y.-U., Park, J.-A., and Kim, S.-B., “Humic acid removal from water by ironcoated sand: A column experiment,” Environ. Eng. Res., 14, 41-47 (2009). https://doi.org/10.4491/eer.2009.14.1.041
  13. Jeon, C.-S., Baek, K., Park, J.-K., Oh, Y.-K., and Lee, S.-D., “Adsorption characteristics of As(V) onto iron-coated zeolite,” J. Hazard. Mater., 163, 804-808 (2009). https://doi.org/10.1016/j.jhazmat.2008.07.052
  14. Mohan, D. and Pittman Jr., C. U., “Arsenic removal from water/wastewater using adsorbents-A critical review,” J. Hazad. Mater., 142, 1-53 (2007). https://doi.org/10.1016/j.jhazmat.2007.01.006
  15. Lee, S., “Geochemistry and partitioning of trace metals in paddy soils affected by metal mine tailings in Korea,” Geoderma, 135, 26-37 (2006). https://doi.org/10.1016/j.geoderma.2005.11.004
  16. Chuang, C. L., Fan, M., Xu, M., Brown, R. C., Sung, S., Saha, B., and Huang, C. P., “Adsorption of arsenic(V) by activated carbon prepared from oat hulls,” Chemosphere, 61, 478-483 (2005). https://doi.org/10.1016/j.chemosphere.2005.03.012
  17. Loukidou, M. X., Matis, K. A., Zouboulis, A. I., and Liakipoulou- Kyriakidou, M., “Removal of As(V) from wastewaters by chemically modified fungal biomass,” Water Res., 37, 4544-4552 (2003). https://doi.org/10.1016/S0043-1354(03)00415-9
  18. Choi, H. D., Cho, J.-M., Baek, K., Yang, J.-S., and Lee, J.-Y., “Influence of cationic surfactant on adsorption of Cr(VI) onto activated carbon,” J. Hazard. Mater., 161, 1565-1568 (2009). https://doi.org/10.1016/j.jhazmat.2008.04.067
  19. Choi, H.-D., Shin, M.-C., Kim, D.-H., Jeon, C.-S., and Baek, K., “Removal characteristics of reactive black 5 using surfactant-modified activated carbon,” Desalination, 223, 290-298 (2008). https://doi.org/10.1016/j.desal.2007.01.224
  20. Choi, H.-D., Jung, W.-S., Cho, J.-M., Ryu, B.-G., Yang, J.-S., and Baek, K., “Adsorption of Cr(VI) onto cationic surfactant-modified activated carbon,” J. Hazard. Mater., 166, 642-646 (2009). https://doi.org/10.1016/j.jhazmat.2008.11.076
  21. Sparks, D. L., “Environmental soil chemistry,” Academic Press 99-110 (1995).

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