Elastomers and Composites

The Rubber Society of Korea (한국고무학회)
권호 표지

Production of Acetylene Black/silica Composite Particles by Adsorption of Polyethylenimine

Polyethyleneimine 흡착에 의한 아세틸렌 블랙/실리카 복합체 입자 제조

  • Lee, Jeong-Woo (Department of Chemical Engineering, Inha University) ;
  • Park, Jung-Hwan (Department of Environmental and Chemical Technology, Inha Technical College) ;
  • Shim, Sang-Eun (Department of Environmental and Chemical Technology, Inha Technical College)
  • 이정우 (인하대학교 화학공학과) ;
  • 박정환 (인하공업전문대학 화공환경과) ;
  • 심상은 (인하공업전문대학 화공환경과)
  • Received : 2010.01.06
  • Accepted : 2010.01.20
  • Published : 2010.03.30

Abstract

The acetylene black/silica composite particles were prepared by a simple and fast method using polyethylenimine (PEI) as a coupling agent. The composite particles were produced via the following two steps; adsorption of PEI on the surface of acetylene black particles and synthesis of silica by sol-gel process. The morphology of the composite particles was a core-shell, and a large number of micropores was created after silica was synthesized on the acetylene black surface.

Keywords

File

Download PDF

Acknowledgement

Supported by : Inha Technical College Research

References

  1. J. B. Donnet, R. C. Bansal, and M. J. Wang, Carbon black, Marcel Dekker, USA (1993).
  2. N. Tsubokawa, T. Satoh, M. Murota, S. Sato, and H. Shimizu, "Grafting of hyperbranched poly(amidoamine) onto carbon black surfaces using dendrimer synthesis methodology", Polym. Adv. Technol., 12, 596 (2001). https://doi.org/10.1002/pat.148
  3. J. Lee, J. Hong, D. W. Park, and S. E. Shim, "Production of Carbon Black/Silica Composite Particles by Adsorption of Poly(vinyl pyrrolidone)", Macromol. Res., 17, 718 (2009). https://doi.org/10.1007/BF03218934
  4. R. M. Casado, P. A. Lovell, P. Navabpour, and J. L. Stanford, "Polymer encapsulation of surfacemodified carbon blacks using surfactant-free emulsion polymerization", Polymer, 48, 2554 (2007). https://doi.org/10.1016/j.polymer.2007.02.063
  5. C. F. Lee, C. Y. Cheng, Y. W. Lee, and Y. C. Wen, "Novel amphiphilic carbon black composite nanoparticles from TEMPO-terminated polymer and TEMPO-terminated block copolymer grafted carbon black", Polymer, 46, 5514 (2005). https://doi.org/10.1016/j.polymer.2005.04.053
  6. E. Papirer, R. Lacroix, and J. B. Donnet, "Chemical modifications and surface properties of carbon blacks", Carbon, 34, 1521 (1996). https://doi.org/10.1016/S0008-6223(96)00103-0
  7. Y. Liu, Zhizhongsu, X. Li, W. Guo, Q. Li, and C. Wu, "Effect of Dispersion of Carbon Black on Electrical and Thermal Properties of Poly(Ethylene Terephthalate)/Carbon Black Composites", J. Macromol. Sci. Part B: Phys., 48, 146 (2009). https://doi.org/10.1080/00222340802561730
  8. D. R. Hwang, J. Hong, J. Lee, and S. E. Shim, "In-Situ Synthesis of PS/(-)Silica Composite Particles in Dispersion Polymerization Using An (${\pm}$) Amphoteric Initiator", Macromol. Res., 16, 329 (2008). https://doi.org/10.1007/BF03218525
  9. J. W. Brinke, S. C. Debnath, L. A. E. M. Reuvekamp, and J. W. M. Noordermeer, "Mechanistic aspects of the role of coupling agents in silica-rubber composites", Compos. Sci. Technol., 63, 1165 (2003). https://doi.org/10.1016/S0266-3538(03)00077-0
  10. N. Rattanasom, T. Saowapark, and C. Deeprasertkul, "Reinforcement of natural rubber with silica/carbon black hybrid filler", Polym. Test., 26, 369 (2007). https://doi.org/10.1016/j.polymertesting.2006.12.009
  11. A. Venkateswara Rao, P. B. Wagh, D. Haranath, P. P. Risbud, and S. D. Kumbhare, "Influence of temperature on the physical properties of TEOS silica xerogels", Ceram. Int., 25, 505 (1999). https://doi.org/10.1016/S0272-8842(97)00085-0
  12. Y. Liu, D. Wu, W. Zhang, X. Jiang, C. He, T. Chung, S. H. Goh, and K. W. Leong, "Polyethylenimine-Grafted Multiwalled Carbon Nanotubes for Secure Noncovalent Immobilization and Efficient Delivery of DNA", Angew. Chem. Int. Ed., 44, 4782 (2005). https://doi.org/10.1002/anie.200500042
  13. W. Yuan, M. Peng, Q. Yu, B. Tang, and Q. Zheng, "Synthesis and Characterization of Polystyrene/Nanosilica Organic-Inorganic Hybrid", Chem. Res. Chin. Univ., 22, 797 (2006). https://doi.org/10.1016/S1005-9040(06)60215-8
  14. U. Vijayalakshmi, A. Balamurugan, and S. Rajeswari, "Synthesis and Characterization of Porous Silica Gels for Biomedical Applications", Trends Biomater. Artif. Organs, 18, 101 (2005).
  15. G. V. Sebastiani, and F.Vecchiocattivi, "Photocatalytic Activity in CH3CN Related to the Surface Properties of $TiO_2$ Powders Prepared by Sol-Gel Method", Inter. J. Photoenergy, 2009, Article ID 905987 (2009).