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Chemical Transformation of Succinic Acid by Using Amberlite IR-120 and the Reusability of Catalyst

Amberlite IR-120를 사용한 숙신산의 화학적 전환과 촉매의 재 사용성

  • Received : 2011.08.10
  • Accepted : 2011.09.28
  • Published : 2011.12.20

Abstract

Dioctyl succinates and succinic anhydride were synthesized from succinic acid in the presence of a cation exchange resin, Amberlite IR-120. The synthesis of dioctyl succinate from succinic acid and octanol was perfomed in 18 h reflux condition with Amberlite IR-120 and the isolated yield of product was over 90%. For the synthesis of succinic anhydride, succinic acid was refluxed in isopropenyl acetate for 18 h with Amberlite IR-120 as a catalyst. The long reaction time was significantly reduced to less than 10 min under microwave irradiation. The catalyst was reusable at least 4 times with keeping product yield of higher than 80%.

Keywords

Microwave irradiation;Succinic anhydride;Esterification;Reuseability;Cation exchange resin

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Cited by

  1. Extraction and recovery optimization of succinic acid using green emulsion liquid membrane containing palm oil as the diluent pp.19447442, 2018, https://doi.org/10.1002/ep.13065

Acknowledgement

Grant : 숙신산계 정밀화학중간체 개발