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Combination of Sequential Batch Reactor (SBR) and Dissolved Ozone Flotation-Pressurized Ozone Oxidation (DOF-PO2) Processes for Treatment of Pigment Processing Wastewater

  • Kim, Jeong-Hyun (Department of Civil and Environmental Engineering, University of Ulsan) ;
  • Kim, Hyung-Suk (Department of Civil and Environmental Engineering, University of Ulsan) ;
  • Lee, Byoung-Ho (Department of Civil and Environmental Engineering, University of Ulsan)
  • Received : 2010.06.27
  • Accepted : 2011.05.16
  • Published : 2011.06.30

Abstract

This study investigates the treatment of pigment wastewater using a sequential batch reactor (SBR) followed by dissolved ozone flotation-pressurized ozone oxidation treatement (DOF-$PO_2$). The process efficiency has been evaluated at the lab scale on the basis of water quality parameters. In addition, the effect of pure oxygen and air was investigated on the removal of COD, BOD, and TN in the SBR process. It was observed that under comparable conditions the removal efficiencies of these water quality parameters using pure oxygen and air were similar. The effect of the recycle rate was also investigated for its impact on the water quality parameters using different ozone dissolving pressures in a DOF process in order to optimise conditions. The results conclude that the use of an SBR and ozone contact by DOF-$PO_2$ is a highly effective treatment for pigment wastewater and aids in the achievement of effluent discharge criteria.

References

  1. Solozhenko EG, Soboleva NM, Goncharuk VV. Decolourization of azodye solutions by Fenton's oxidation. Water Res. 1995;29:2206-2210. https://doi.org/10.1016/0043-1354(95)00042-J
  2. Kim YO, Nam HU, Park YR, Lee JH, Park TJ, Lee TH. Fenton oxidation process control using oxidation-reduction potential measurement for pigment wastewater treatment. Korean J. Chem. Eng. 2004;21:801-805. https://doi.org/10.1007/BF02705523
  3. Lin SH, Lin CM. Treatment of textile waste effluents by ozonation and chemical coagulation. Water Res. 1993;27:1743-1748. https://doi.org/10.1016/0043-1354(93)90112-U
  4. Jo HJ, Park EJ, Cho K, Kim EH, Jung J. Toxicity identification and reduction of wastewaters from a pigment manufacturing factory. Chemosphere 2008;70:949-957. https://doi.org/10.1016/j.chemosphere.2007.08.018
  5. Kapdan IK, Ozturk R. Effect of operating parameters on color and COD removal performance of SBR: sludge age and initial dyestuff concentration. J. Hazard. Mater. 2005;123:217-222. https://doi.org/10.1016/j.jhazmat.2005.04.013
  6. Ganesh R, Balaji G, Ramanujam RA. Biodegradation of tannery wastewater using sequencing batch reactor--respirometric assessment. Bioresour. Technol. 2006;97:1815-1821. https://doi.org/10.1016/j.biortech.2005.09.003
  7. Dangcong P, Bernet N, Delgenes JP, Moletta R. Effects of oxygen supply methods on the performance of a sequencing batch reactor for high ammonium nitrification. Water Environ. Res. 2000;72:195-200. https://doi.org/10.2175/106143000X137284
  8. Kargi F, Uygur A. Nutrient removal performance of a sequencing batch reactor as a function of the sludge age. Enzyme Microb. Technol. 2002;31:842-847. https://doi.org/10.1016/S0141-0229(02)00209-0
  9. Shu HY, Chang MC. Decolorization effects of six azo dyes by $O_3,\;UV/O_3\;and\;UV/H_2O_2$ processes. Dyes Pigments 2005;65:25-31. https://doi.org/10.1016/j.dyepig.2004.06.014
  10. Tosik R. Dyes color removal by ozone and hydrogen peroxide: some aspects and problems. Ozone Sci. Eng. 2005;27:265-271. https://doi.org/10.1080/01919510591005905
  11. Meric S, Kaptan D, Olmez T. Color and COD removal from wastewater containing Reactive Black 5 using Fenton's oxidation process. Chemosphere 2004;54:435-441. https://doi.org/10.1016/j.chemosphere.2003.08.010
  12. Gutowska A, Kaluzna-Czaplinska J, Jozwiak WK. Degradation mechanism of Reactive Orange 113 dye by $H_2O_2/Fe^{2+}$ and ozone in aqueous solution. Dyes Pigments 2007;74:41-46. https://doi.org/10.1016/j.dyepig.2006.01.008
  13. Chung KT, Stevens SE. Degradation azo dyes by environmental microorganisms and helminths. Environ. Toxicol. Chem. 1993;12:2121-2132.
  14. Beydilli MI, Pavlostathis SG, Tincher WC. Decolorization and toxicity screening of selected reactive azo dyes under methanogenic conditions. Water Sci. Technol. 1998;38:225-232. https://doi.org/10.1016/S0273-1223(98)00531-9
  15. Konsowa AH. Decolorization of wastewater containing direct dye by ozonation in a batch bubble column reactor. Desalination 2003;158:233-240. https://doi.org/10.1016/S0011-9164(03)00458-2
  16. Saroj DP, Kumar A, Bose P, Tare V, Dhopavkar Y. Mineralization of some natural refractory organic compounds by biodegradation and ozonation. Water Res. 2005;39:1921-1933. https://doi.org/10.1016/j.watres.2005.03.020
  17. Choi JW, Song H, Lee W, Koo KK, Han C, Na BK. Reduction of COD and color of acid and reactive dyestuff wastewater using ozone. Korean J. Chem. Eng. 2004;21:398-403. https://doi.org/10.1007/BF02705427
  18. Lee BH, Song WC, Manna B, Ha JK. Dissolved ozone flotation (DOF)--a promising technology in municipal wastewater treatment. Desalination 2008;225:260-273. https://doi.org/10.1016/j.desal.2007.07.011
  19. Gurol MD. Factors controlling the removal of organic pollutants in ozone reactors. J. Am. Water Works Assoc. 1985;77:55-60.
  20. Yurteri C, Gurol MD. Removal of dissolved organic contaminants by ozonation. Environ. Prog. 1987;6:240-245. https://doi.org/10.1002/ep.670060411
  21. Qingshi Z, Cunli L, Zhengyu X. A study of contacting systems in water and wastewater disinfection by ozone. 1. Mechanism of ozone transfer and inactivation related to the contacting method selection. Ozone Sci. Eng. 1989;11:169-188. https://doi.org/10.1080/01919518908552434
  22. Fuchun X, Cunli L. Mass balance analysis of ozone in a conventional bubble column. Ozone Sci. Eng. 1990;12:269-279. https://doi.org/10.1080/01919519008552196
  23. Shin WT, Mirmiran A, Yiacoumi S, Tsouris C. Ozonation using microbubbles formed by electric fields. Sep. Purif. Technol. 1999;15:271-282. https://doi.org/10.1016/S1383-5866(98)00107-5
  24. Rosal R, Rodriguez A, Zerhouni M. Enhancement of gas-liquid mass transfer during the unsteady-state catalytic decomposition of ozone in water. Appl. Catal. A 2006;305:169-175. https://doi.org/10.1016/j.apcata.2006.02.059
  25. Mitani MM, Keller AA, Sandall OC, Rinker RG. Mass transfer of ozone using a microporous diffuser reactor system. Ozone Sci. Eng. 2005;27:45-51. https://doi.org/10.1080/01919510590908995
  26. Zhou H, Smith DW, Stanley SJ. Modeling of dissolved ozone concentration profiles in bubble columns. J. Environ. Eng. 1994;120:821-840. https://doi.org/10.1061/(ASCE)0733-9372(1994)120:4(821)
  27. Eaton AD, Clesceri LS, Greenberg AE. Standard methods for the examination of water and wastewater. 19th ed. Washington, DC: American Public Health Association; 1995. p. 1043-1055.
  28. Adams CD, Gorg S. Effect of pH and gas-phase ozone concentration on the decolorization of common textile dyes. J. Environ. Eng. 2002;128:293-298. https://doi.org/10.1061/(ASCE)0733-9372(2002)128:3(293)

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