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Synthesis and Characterization of Bio-Elastomer Based on Vegetable Oils

식물성 오일 기반 바이오 탄성체의 합성과 특성

  • Lee, Hyeok (Department of Polymer Science & Enginering, Gyeongsang National University) ;
  • Kwak, Kyung-Hwan (Department of Polymer Science & Enginering, Gyeongsang National University) ;
  • Kim, Jin-Kuk (Department of Polymer Science & Enginering, Gyeongsang National University)
  • 이혁 (경상대학교 고분자공학과) ;
  • 곽경환 (경상대학교 고분자공학과) ;
  • 김진국 (경상대학교 고분자공학과)
  • Received : 2012.01.12
  • Accepted : 2012.01.27
  • Published : 2012.03.31

Abstract

Novel bio-polybutadiene polymers with controlled molecular weight (MW), MW distribution, chemical composition and micro structure were synthesized by a living anionic polymerization of butadiene and the subsequent coupling reaction of the thus obtained living polybutadiene and a vegetable oil. Anionic polymerization of butadiene was carried out in THF solvent using n-BuLi initiator. The resulting living polybutadienyllithium polymer was then reacted with epoxidized soybean oil (ESO) to obtain a star-polymer of polybutadiene and vegitable oil. Three different bio-elastomers were prepared by coupling living polybutadienes of MWs 1000, 5000 and 1000g/mol with ESO. The molecular structure and MW of the polybutadienes and bioelastomers were characterized by $^1H$-NMR, FTIR and GPC techniques.

Acknowledgement

Grant : 환경융합신기술개발사업

Supported by : 환경부

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