Elastomers and Composites

The Rubber Society of Korea (한국고무학회)
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Synthesis of Magnetic Polystyrene-Polyimide Core-Shell Microsphere

자성 폴리스티렌-폴리이미드 Core-Shell 마이크로스피어의 합성

  • Ahn, Byung-Hyun (Department of Material Engineering, Pukyong National University)
  • 안병현 (부경대학교 재료공학과)
  • Received : 2012.04.12
  • Accepted : 2012.04.19
  • Published : 2012.06.30

Abstract

Polystyrene-polyimide core-shell microsphere was prepared by dispersion polymerization using poly(amic acid) as the stabilizer. Iron oxide was formed at the microsphere by thermal decomposition of iron pentacarbonyl impregnated in the microsphere. The magnetic polystyrene-polyimide microsphere was monodisperse and the size was about 500 nm. The magnetic polystyrene-polyimide microsphere had 40% of iron oxide, which was identified as $Fe_3O_4$ by X-ray diffraction.

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Acknowledgement

Supported by : 부경대학교

References

  1. K. Sugibayashi, Y. Morimoto, T. Nadai, and Y. Kato, Chem. Pharm. Bull., 25, 3433 (1997).
  2. Y. Haik, V. Pai, and C. J. Chen, J. Magn. Magn. Mater., 194, 254 (1999). https://doi.org/10.1016/S0304-8853(98)00559-9
  3. C. H. Setchell, J. Chem. Technol. Biotechnol. B, 35, 175 (1985). https://doi.org/10.1002/jctb.280350302
  4. M. Shinkai, H. Honda, and T. Kobayashi, Biocatalysis, 5, 61 (1991). https://doi.org/10.3109/10242429109014855
  5. A. Kondo, H. Kamura, and K. Higashitani, Appl. Microbiol. 41, 99 (1994). https://doi.org/10.1007/BF00166089
  6. M. Meza, U. Hafeli, W. Schutt, and M. Zborowski (Eds.), Scientific and Clinical Applications of Magnetic Carriers, Plenum, New York, 1997, p. 303.
  7. A. Elaissari, M. Rodrigue, F. Meunier, and C. Herve, J. Magn. Magn. Mater., 225, 127 (2001). https://doi.org/10.1016/S0304-8853(00)01240-3
  8. P. K. Gupta and C. T. Hung, Life Sci., 44, 175 (1989). https://doi.org/10.1016/0024-3205(89)90593-6
  9. N. Yanase, H. Noguchi, H. Asakura, and T. Suzuta, J. Appl. Polym. Sci., 50, 765 (1993). https://doi.org/10.1002/app.1993.070500504
  10. J. Ugelstad, A. Berge, T. Ellingsen, R. Schmid, T. N. Nilsen, P. C. Mork, P. Stenstad, E. Hornes, and O. Olsvik, Prog. Polym. Sci., 17, 87 (1992). https://doi.org/10.1016/0079-6700(92)90017-S
  11. Z. Ma, Y. Guan, and H. Liu, J. Polym. Sci. Part A, 43, 3433 (2005).
  12. N. A. D. Burke, H. D. H. Stöver, and F. P. Dawson, Chem. Mater., 14, 4752 (2002). https://doi.org/10.1021/cm020126q
  13. K. Butter, A. P. Philips, and G. J. Vroege, J. Magn. Magn. Mater., 252, 1 (2002). https://doi.org/10.1016/S0304-8853(02)00620-0
  14. M. Okubo, H. Minami, and T. Komura, J. Appl. Polym. Sci., 88, 428 (2003). https://doi.org/10.1002/app.11720
  15. S. Watanabe, K. Ueno, K. Kudoh, M. Murata, and Y. Masuda, Macromol. Rapid Commun., 21, 1323 (2000). https://doi.org/10.1002/1521-3927(20001201)21:18<1323::AID-MARC1323>3.0.CO;2-X
  16. S. Kobayahsi, H, Uyama, S. W. Lee, and Y. Matsumoto, J. Polym. Sci. Part A, 31, 3133 (1993). https://doi.org/10.1002/pola.1993.080311229
  17. E. Bourgeat-Lami and A. Guyot, Polym. Bull., 35, 691 (1995). https://doi.org/10.1007/BF00294951