DOI QR코드

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Thermophysical Properties of Acetophenone with Ethylchloroacetate at Temperatures of 303.15, 313.15 and 323.15 K

  • Saravanakumar, K. ;
  • Baskaran, R. ;
  • Kubendran, T.R.
  • 투고 : 2011.08.12
  • 심사 : 2012.07.03
  • 발행 : 2012.08.20

초록

Densities, viscosities, refractive indices and speed of sounds of the binary mixtures of Acetophenone with Ethylchloroacetate were measured over the entire mole fractions at (303.15, 313.15 and 323.15) K. From these experimental results, excess molar volume $V^E$, viscosity deviation ${\Delta}{\eta}$, refractive index deviation ${\Delta}n_D$, deviations in speed of sound ${\Delta}u$, deviations in isentropic compressibility ${\Delta}k_s$ and excess intermolecular free length ${\Delta}L_f$ were calculated. The viscosity data have been correlated with the equations of Grunberg and Nissan, Hind et al., Tamura and Kurata, Katti and Chaudri, Sedgwick, Krishnan-Laddha and McAllister. The thermo physical properties under study were fit to the Jouyban-Acree model. The excess values were correlated using Redlich-Kister polynomial equation to obtain their coefficients and standard deviations. It was found that in all cases, the data obtained fitted with the values correlated by the corresponding models very well. The results are interpreted in terms of molecular interactions occurring in the solution.

키워드

Viscosity;Density;Refractive index;Ultrasonic velocity;Molecular interactions

참고문헌

  1. Kim, E. S.; Marsh, K. N. J. Chem. Eng. Data 1988, 33, 288. https://doi.org/10.1021/je00053a020
  2. Mchaweh, A.; A. Alsaygh, A.; Mosh-Feghian, M. A. Fluid Phase Equilib. 2004, 224, 157. https://doi.org/10.1016/j.fluid.2004.06.054
  3. Kenart, C. M.; Kenart, W. Phys. Chem. Liq. 2000, 38, 155. https://doi.org/10.1080/00319100008030266
  4. Baskaran, R.; Kubendran, T. R. J. Chem. Eng. Data 2008, 53, 978. https://doi.org/10.1021/je700714m
  5. Baskaran, R.; Kubendran, T. R. J. Chem. Eng. Data 2008, 53, 1956. https://doi.org/10.1021/je8002699
  6. Grunberg, L.; Nissan, A. Nature 1949, 164, 799.
  7. Hind, R. K.; Mclaughlin, E.; Ubbelohde, A. R. Trans. Faraday Soc. 1960, 56, 328. https://doi.org/10.1039/tf9605600328
  8. Tamura, M.; Kurata, M. Bull. Chem. Soc. Jpn. 1952, 25, 32. https://doi.org/10.1246/bcsj.25.32
  9. Katti, P. K.; Chaudhari, M. M. J. Chem. Eng. Data 1964, 9, 442. https://doi.org/10.1021/je60022a047
  10. Sedgwick, T. O. The viscosity and thermal conductivity of liquid mixtures. Ph.D Thesis, Brooklyn Polytechnic Institute, 1962.
  11. McAllister, R. A. AIChE Journal 1960, 6, 427. https://doi.org/10.1002/aic.690060316
  12. Krishnan, M. R. V.; Laddha, G. S. Indian Chemical Engineer, Trans. 1963, 57.
  13. Jouyban, A.; Khoubnasabjafari, M.; Vaezgharamaleki, Z.; Fekari, Z.; Jr. Acree, W. E. Chem. Pharm. Bull. 2005, 53, 519. https://doi.org/10.1248/cpb.53.519
  14. Redlich, O.; Kister, A. T. Ind. Eng. Chem. 1948, 40, 345. https://doi.org/10.1021/ie50458a036
  15. Perrin, D. D.; W. L. F. Armerego Purification of Laboratory Chemistry, 3rd ed.; Pergamon press: Oxford, 1988.
  16. Riddick, J. A.; W. B. Bunger; Sakano, T. K. Orgarnic Solvent, 4th ed.; Wiley-Interscience: New York, 1986.
  17. Treszczanowicz, A. J.; Kiyohara, O.; Benson, G. C. J. Chem. Thermodyn. 1981, 13, 253. https://doi.org/10.1016/0021-9614(81)90125-7
  18. Syamala, V.; Venkateshwarlu, P.; Sivakumar, K. J. Chem.Eng. Data 2006, 51, 928. https://doi.org/10.1021/je050413l
  19. Manapragada, V. R.; Sudhir, M.; Manapragada, S. K. J. Chem. Eng. Data 2010, 55, 5946. https://doi.org/10.1021/je100715x
  20. Surendranath, K. N.; K. Ramanjaneyulu, K.; Krishnaiah, A. Fluid Phase Equilb. 1990, 59, 225. https://doi.org/10.1016/0378-3812(90)85037-B
  21. Syeda, A. B.; Ranjith, K. B.; Koppula, A. J.; Sathyanarayana, B.; Sathyanarayana, N. J. Chem. Eng. Data 2010, 55, 1067. https://doi.org/10.1021/je900525f
  22. Sathyanarayana, N.; Sathyanarayana, B.; Savitha, J. T. J. Chem. Eng. Data 2007, 52, 405. https://doi.org/10.1021/je060343y
  23. Oswal, S. L.; Patel, N. B. J. Chem. Eng. Data 2000, 45, 225. https://doi.org/10.1021/je980305h
  24. Rama, R. G. V.; Viswanatha, S. A.; Rambabu, C. Indian J. Pure & Appl. Phys. 2004, 42, 820.
  25. Jyoti, N. N.; Mrityunjaya, I. A.; Aminabhavi, T. M. J. Chem. Eng. Data 2007, 47, 964.
  26. Roux, A.; Desnoyers, J. Indian Acad. Proc., Chem. Soc. 1978, 78, 435.
  27. Fort, R. J.; Moore, W. R. Trans. Faraday Soc. 1966, 62, 1112. https://doi.org/10.1039/tf9666201112
  28. Iloukhani, H.; Rostami, Z. J. Chem. Eng. Data 2007, 52, 921. https://doi.org/10.1021/je600519p

피인용 문헌

  1. Thermophysical and thermoacoustical properties of acetophenone with ethyl butyrate at temperatures of 303.15, 313.15, and 323.15 K vol.25, pp.2, 2016, https://doi.org/10.1134/S1810232816020077
  2. Thermo-physical properties for the binary system of propiophenone-methyl acetate at 303.15–313.15 K vol.89, pp.10, 2015, https://doi.org/10.1134/S0036024415100040
  3. Total ionization cross section of cyclic organic molecules vol.150, pp.6, 2019, https://doi.org/10.1063/1.5081841