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Desorption Kinetics and Removal Characteristics of Pb-Contaminated Soil by the Soil Washing Method: Mixing Ratios and Particle Sizes

Lee, Yun-Hee;Oa, Seong-Wook

  • Received : 2012.03.13
  • Accepted : 2012.08.10
  • Published : 2012.09.30

Abstract

Pb-contaminated soil at a clay shooting range was analyzed by the sequential extraction method to identify metal binding properties in terms of detrital and non-detrital forms of the soil. Most of the metals in the soils existed as non-detrital forms, exchangeable and carbonate-bound forms, which could be easily released from the soil by a washing method. Therefore, the characteristics of Pb desorption for remediation of the Pb-contaminated soil were evaluated using hydrochloric acid (HCl) by a washing method. Batch experiments were performed to identify the factors influencing extraction efficiency. The effects of the solid to liquid (S/L) ratio (1:2, 1:3, and 1:4), soil particle size, and extraction time on the removal capacity of Pb by HCl were evaluated. Soil samples were collected from two different areas: a slope area (SA) and a land area (LA) at the field. As results, the optimal conditions at 2.8 to 0.075 mm of particle size were 1:3 of the S/L ratio and 10 min of extraction time for SA, and 1:4 of the S/L ratio and 5 min of extraction time for LA. The characteristics of Pb desorption were adequately described by two-reaction kinetic models.

Keywords

Hydrochloric acid;Lead;Solid to liquid ratio;Subsequent extraction method;Two-reaction model

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