Elastomers and Composites

The Rubber Society of Korea (한국고무학회)
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Synthesis of Ionic Elastomer Based on Styrene-Butadiene Rubber Containing Methacrylic Acid

Methacrylic Acid가 도입된 Styrene-Butadiene Rubber를 기반으로 한 Ionic Elastomer 합성

  • Kim, Ki-Hyun (Department of Chemical and Biomolecular Engineering, Pusan National University) ;
  • Lee, Jong-Yeop (R&BD Center, Kumho Petrochemical) ;
  • Choi, Joon-Myeong (Department of Polymer and Science Engineering, Pusan National University) ;
  • Kim, Hee-Jung (Department of Polymer and Science Engineering, Pusan National University) ;
  • Seo, Byeongho (Department of Chemical and Biomolecular Engineering, Pusan National University) ;
  • Kim, Bong-Soo (Department of Polymer and Science Engineering, Pusan National University) ;
  • Kwag, Gwang-Hoon (R&BD Center, Kumho Petrochemical) ;
  • Paik, Hyun-Jong (Department of Polymer and Science Engineering, Pusan National University) ;
  • Kim, Wonho (Department of Chemical and Biomolecular Engineering, Pusan National University)
  • Received : 2012.12.17
  • Accepted : 2012.12.28
  • Published : 2013.03.31

Abstract

A new terpolymer, styrene-butadiene-benzyl methacrylate copolymer (BzMA-SBR) was synthesized by emulsion polymerization. After polymerization, XSBR ionomer was prepared by deprotection of benzyl group of BzMA through hydrolysis with NaOH. Carboxyl group contents can be controlled by changing the initial feed contents of BzMA. Structure of BzMA-SBR and XSBR were characterized by FTIR, $^1H$ NMR and DSC.

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Acknowledgement

Supported by : 지식경제부

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