DOI QR코드

DOI QR Code

Highly active and trans-1,4-specific polymerization of 1,3-butadiene catalyzed by bis(benzimidazolyl)amine chromium complexes activated with methylaluminoxane

메틸알루미녹산으로 활성화시킨 고활성 bis(benzimidazolyl)amine 크롬 착물을 이용한 부타디엔 중합에 의한 트랜스 폴리부타디엔 제조

  • Moon, Byeong Kyu (The WCU Center for Synthetic Polymer Bioconjugate Hybrid Materials, Department of Polymer Science and Engineering, Pusan National University) ;
  • Song, Ga Young (The WCU Center for Synthetic Polymer Bioconjugate Hybrid Materials, Department of Polymer Science and Engineering, Pusan National University) ;
  • Zhang, Lin (The WCU Center for Synthetic Polymer Bioconjugate Hybrid Materials, Department of Polymer Science and Engineering, Pusan National University) ;
  • Shin, Jin Young (The WCU Center for Synthetic Polymer Bioconjugate Hybrid Materials, Department of Polymer Science and Engineering, Pusan National University) ;
  • Chang, Hyuk Chul (The WCU Center for Synthetic Polymer Bioconjugate Hybrid Materials, Department of Polymer Science and Engineering, Pusan National University) ;
  • Shim, Sang Eun (Department of Chemical Engineering, Inha University) ;
  • Yun, Ju Ho (Enviromental Materials & Components R&D Center, Korea Automotive Technology Institute) ;
  • Kim, Il (The WCU Center for Synthetic Polymer Bioconjugate Hybrid Materials, Department of Polymer Science and Engineering, Pusan National University)
  • 문병규 (부산대학교 고분자공학과) ;
  • 송가영 (부산대학교 고분자공학과) ;
  • 장린 (부산대학교 고분자공학과) ;
  • 신진영 (부산대학교 고분자공학과) ;
  • 장혁철 (부산대학교 고분자공학과) ;
  • 심상은 (인하대학교 화학공학과) ;
  • 윤주호 (자동차부품연구원) ;
  • 김일 (부산대학교 고분자공학과)
  • Received : 2012.12.24
  • Accepted : 2013.01.10
  • Published : 2013.03.31

Abstract

A family of Cr(III) complexes supported on tridentate dibenzimidazolyl ligands having a general formula: $[N(CH_3)(CH_2)_2(Bm-R)_2]CrCl_3$ [where Bm = benzimidazolyl, R = H (3a); -Me(3b); -Bn (3c)] have been synthesized and utilized them for the trans-1,4-specific polymerizations of 1,3-butadiene (BD), activated with methylalumoxane (MAO). The activity of BD polymerizations was sensitive to the type of ligand on the Cr metal, so that the activity decreases in the order of 3a > 3c > 3b. All the catalysts combined with MAO yielded polybutadienes with perfect trans-1,4 structure with moderate molecular weight.

Acknowledgement

Supported by : Ministry of Knowledge Economy

References

  1. Thiele S K H and Wilson D R, J. Macromol. Sci. C: Polym. Rev., C43, 581 (2003).
  2. L. Friebe, O. Nuyken and W. Obrecht, Adv. Polym. Sci., 204, 1 (2006). https://doi.org/10.1007/12_094
  3. Ricci G, Sommazzi, A, Masi F, Ricci M, Bogliaa A, and G. Leonea, Coord. Chem. Rev., 254, 661 (2010). https://doi.org/10.1016/j.ccr.2009.09.023
  4. Peluso A, Improta R, and Zambelli A, Organometallics, 19, 411 (2000). https://doi.org/10.1021/om980940g
  5. Tobisch, S, Organometallics, 22, 2729 (2003). https://doi.org/10.1021/om030059p
  6. Costabile C, Guerra G, Longo P, and Pragliola S, Macromolecules, 37, 2016 (2004). https://doi.org/10.1021/ma035892c
  7. Iwamoto M and Yuguchi S, Polym. Lett., 5, 1007 (1967). https://doi.org/10.1002/pol.1967.110051106
  8. Hermes A R and Girolami G S, Inorg. Chem., 27, 1775 (1988). https://doi.org/10.1021/ic00283a021
  9. Nakayama Y, Sogo K, Cai Z, Yasuda H, and Shiono T, Polym. Int., 60, 692 (2011). https://doi.org/10.1002/pi.3008
  10. Bianchini C, Mantovani G, Meli A, Migliacci F, Zanobini F, Laschi F, and Sommazzi A, Eur. J. Inorg. Chem., 1620 (2003).
  11. Appukuttan V, Zhang L, Ha C -S, and I Kim, Polymer, 50, 1150 (2009). https://doi.org/10.1016/j.polymer.2008.12.047
  12. Kwaskowska-Chec E, Kubiak M, Glowiak T, and Ziolkowski J J, J. Chem. Crystallogr., 25, 37 (1995). https://doi.org/10.1007/BF01666192
  13. Lee G M, Appukuttan V K, Suh H, Ha S -S, and Kim I, Catal. Lett., 141, 1608 (2011). https://doi.org/10.1007/s10562-011-0697-9
  14. Perdew J P and Wang Y, Phys. Rev. B, 45, 13244 (1992). https://doi.org/10.1103/PhysRevB.45.13244
  15. Bakalarski G, Grochowski P, Kwiatkowski J S, Lesyng B, and Leszczynski J, Chem. Phys., 204, 301 (1996). https://doi.org/10.1016/0301-0104(95)00413-0
  16. Mulliken R S, J. Chem. Phys., 23, 1833 (1955). https://doi.org/10.1063/1.1740588
  17. Hirshfeld F L, Theor. Chim. Acta B, 44, 129 (1977). https://doi.org/10.1007/BF00549096
  18. Sato H, Takebayashi K, and Tanaka Y, Macromolecules, 20, 2418 (1987). https://doi.org/10.1021/ma00176a016