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A Kinetic Study on the Oxidation of Indole by Peroxomonosulphate in Acetonitrile Solvent

  • Kavery, Muniyappan ;
  • Govindasamy, Chandramohan ;
  • Johnson, Stephen
  • Received : 2012.09.05
  • Accepted : 2013.02.19
  • Published : 2013.04.20

Abstract

Kinetics of oxidation of indole by peroxomonosulphate (PMS) in aqueous acetonitrile medium has been investigated. The reaction follows a total second order, first order each with respect to [Indole] and [PMS]. The rate of the reaction was not affected by added [$H^+$]. Variation of ionic strength (${\mu}$) had no influence on the rate. Increase of percentage of acetonitrile decreased the rate. Absen ce of any polymerization indicated a nonradical pathway. Activation and thermodynamic parameters have bee n computed. A suitable kinetic scheme based on these observations is proposed. The reactivity of PMS towards Indole was found to be higher than that with peroxodisulphate.

Keywords

Kinetics;Mechanism;Oxidation;Indole;Peroxomonosulphate (PMS)

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