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톱다리개미허리노린재 페로몬, (E)-2-hexenyl (E)-2-hexenoate과 (E)-2-hexenyl (Z)-3-hexenoate의 합성

A facile synthesis of (E)-2-hexenyl (E)-2-hexenoate and (E)-2-hexenyl (Z)-3-hexenoate, pheromone components of Riptortus pedestris

  • 김준헌 (경상대학교 응용생명과학부(BK21)) ;
  • 박정규 (경상대학교 농업생명과학연구원)
  • Kim, Junheon (Division of Applied Life Science (BK21), Gyeongsang National University) ;
  • Park, Chung Gyoo (Institute of Agriculture and Life Sciences, Gyeongsang National University)
  • 투고 : 2012.11.09
  • 심사 : 2013.04.05
  • 발행 : 2013.08.30

초록

톱다리개미허리노린재의 페로몬 성분인 (E)-2-hexenyl (E)-2-hexenoate (1) 과 (E)-2-hexenyl (Z)-3-hexenoate (2)의 합성에 있어 Steglich 에스테르화 반응의 최적 조건을 검토하였다. (E)-2-헥센산 또는 (Z)-3-헥센산에 대하여 1-1.5 당량의 디사이클로카보다이이미드 (DCC), 1.5-2.0 당량의 (E)-2-헥센놀과 0.1 당량의 4-디메틸아미노피리딘(DMAP)과 반응하였을 때, 각각 76-78% 와 87-91%의 수율로 1과 2를 얻었다.

과제정보

연구 과제 주관 기관 : Rural Development Administration

참고문헌

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피인용 문헌

  1. Thunberg (Hemiptera: Coreidae) vol.47, pp.2, 2017, https://doi.org/10.1111/1748-5967.12204
  2. (Hymenoptera: Encyrtidae) pp.09312048, 2017, https://doi.org/10.1111/jen.12468