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Measurement of 1,4-dioxane in surface water by headspace GC-MS

GC-MS에 의한 지표수에서 1,4-Dioxane의 측정

  • Hong, Seon-Haw (Geum River Environment Research Center, National Institute of Environmental Research) ;
  • Lee, Jun-Bae (Geum River Environment Research Center, National Institute of Environmental Research) ;
  • Lee, Soo-Hyung (Geum River Environment Research Center, National Institute of Environmental Research) ;
  • Lim, Hyun-Hee (Department of Environmental Science, Kongju National University) ;
  • Shin, Ho-Sang (Department of Environmental Education, Kongju National University)
  • 홍선화 (국립환경과학원 금강물환경연구소) ;
  • 이준배 (국립환경과학원 금강물환경연구소) ;
  • 이수형 (국립환경과학원 금강물환경연구소) ;
  • 임현희 (공주대학교 환경과학과) ;
  • 신호상 (공주대학교 환경교육과)
  • Received : 2013.10.15
  • Accepted : 2014.01.20
  • Published : 2014.02.25

Abstract

1,4-Dioxane was classified as a Group 2B carcinogen by the International Agency for Research on Cancer. The compound was measured in surface water with a headspace gas chromatographic mass spectrometric detection. A 5 mL water sample was placed in a 10 mL headspace vial and saturated with NaCl, and the solution was spiked with 1,4-dioxane-d8 as an internal standard and sealed with a cap. Water samples were collected from twenty-two basins of Gum-River on June and September 2012, respectively. As a result, 1,4-dioxane was detected in the concentration range of $0.49-43.0{\mu}g/L$ (mean $2.0{\mu}g/L$) in the frequency of about 30% in surface water samples.

Keywords

1,4-Dioxane;surface water;headspace extraction;gas chromatography-mass spectrometry

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