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Effect of Chrome Substitution on Coloration Characteristics of Black Ceramic Pigments

크롬 치환에 따른 흑색 세라믹 안료의 발색 특성 연구

  • Lee, Ji-Hyeon (Icheon Branch, Korea Institute of Ceramic Engineering and Technology) ;
  • Hwang, Hae-Jin (Division of Material Science and Engineering, Inha University) ;
  • Kim, Jin-Ho (Icheon Branch, Korea Institute of Ceramic Engineering and Technology) ;
  • Hwang, Kwang-Taek (Icheon Branch, Korea Institute of Ceramic Engineering and Technology) ;
  • Han, Kyu-Sung (Icheon Branch, Korea Institute of Ceramic Engineering and Technology)
  • 이지현 (한국세라믹기술원 이천분원) ;
  • 황해진 (인하대학교 신소재공학과) ;
  • 김진호 (한국세라믹기술원 이천분원) ;
  • 황광택 (한국세라믹기술원 이천분원) ;
  • 한규성 (한국세라믹기술원 이천분원)
  • Received : 2014.07.29
  • Accepted : 2014.09.03
  • Published : 2014.09.30

Abstract

The properties of black ceramic pigments including thermal and glaze stability were systematically investigated so that these pigments could be used to decorate porcelain products. Various compositions of $(Ni,Mn)(Fe,Cr,Mn)_2O_4$ and $Co(Fe,Cr)_2O_4$ powders were synthesised using a solid state reaction method. The obtained $Co(Fe,Cr)_2O_4$ and $(Ni,Mn)(Fe,Cr,Mn)_2O_4$ powders showed single phases of spinel structure after calcination processes at $1000^{\circ}C$ and $1200^{\circ}C$, respectively. CIE $L^*a^*b^*$ colourimetric parameters of glazed $Co(Fe,Cr)_2O_4$ and $(Ni,Mn)(Fe,Cr,Mn)_2O_4$ pigments were analyzed according to the different amounts of Cr substitution. In addition, the amount of $Cr^{+6}$ remaining in the $Co(Fe,Cr)_2O_4$ and $(Ni,Mn)(Fe,Cr,Mn)_2O_4$ pigments was also measured.

Acknowledgement

Grant : 잉크젯프린팅 포셀린 제품용 고화도 나노세라믹 발색잉크 제조

Supported by : 미래창조과학부, 산업통상지원부

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