시효열처리 및 UNSM 처리에 따른 316L 스테인리스강의 입계부식거동

Lee, J.H.;Kim, Y.S.

  • 투고 : 2015.11.03
  • 심사 : 2015.12.14
  • 발행 : 2015.12.31


Austenitic stainless steels have been widely used in many engineering fields because of their high corrosion resistance and good mechanical properties. However, welding or aging treatment may induce intergranular corrosion, stress corrosion cracking, pitting, etc. Since these types of corrosion are closely related to the formation of chromium carbide in grain boundaries, the alloys are controlled using methods such as lowering the carbon content, solution heat treatment, alloying of stabilization elements, and grain boundary engineering. This work focused on the effects of aging and UNSM (Ultrasonic Nano-crystal Surface Modification) on the intergranular corrosion of commercial 316L stainless steel and the results are discussed on the basis of the sensitization by chromium carbide formation and carbon segregation, residual stress, grain refinement, and grain boundary engineering.


316L stainless steel;UNSM;Intergranular corrosion;Sensitization;Carbide formation;Carbon segregation;Residual stress;Grain refinement;Grain boundary engineering


  1. S. S. Hwang, Corros. and Protect., 12, 1 (2013).
  2. V. Azar, B. Hashemi, and M. R. Yazdi, Surf. Coat. Tech., 204, 3546 (2010).
  3. D. H. Hur, M. S. Choi, D. H. Lee, M. H. Song, S. J. Kim, and J. H. Han, Nucl. Eng. Des., 227, 155 (2004),
  4. P. Sanjurjo, C. Rodriguez, I. F. Pariente, F. J. Belzunce, and A. F. Canteli, Procedia Eng., 2, 1539 (2010).
  5. O. Badran, N. Kloub, and M. Al-Tal, American J. Appli. Sci., 5, 1397 (2008).
  6. M. E. Matarneh, Adv. Theor. Appli. Mech., 5, 45 (2012).
  7. H. Kumar, S. Singh, and P. Kumar, J. Eng. Sci. Emerging Technol., 5, 12 (2013).
  8. P. Peyre, C. Braham, J. Ledion, L. Berthe, and R. Fabbro, J. of Mater. Eng. Perform., 9, 656 (2000).
  9. U. Trdan and J. Grum, Corros. Sci., 59, 324 (2012).
  10. C. S. Montross, T. Wei, L. Ye, G. Clark, and Y. W. Mai, J. Fatigue, 24, 1021 (2002).
  11. A. Telang, C. Ye, A. Gill, S. Teysseyre, S. R. Mannava, D. Qian, and W. K. Vasudevan, proceedings of the 16th International Conference on Environmental Degradation of Materials in Nuclear Power System-Water Reactors, the Grove Park Inn in Asheville, NC, USA, August (2013).
  12. M. A. M. Azhari, Effects of waterjet treatment on surface integrity of metals and its optimization, Dr.-Ing. Dissertation, Technische Universitat Kaierslautern, Mai (2014).
  13. A. K. Gujba and M. Medraj, Materials, 7, 7925 (2014).
  14. C. Ye, A. Telang, A. S. Gill, S. Suslov, Y. Idell, K. Zweiacker, J. M. K. Wiezorek, Z. Zhou, D. Qian, S. R. Mannava, and V. K. Vasudevan, Mater. Sci. Eng A, 613, 274 (2014).
  15. H. S. Lee, D. S. Kim, J. S. Jung, Y. S. Pyoun, and K. Shin, Corros. Sci., 51, 2826 (2009).
  16. Y. S. Pyun, J. H. Park, C. M. Suh, A. Amanov, and J. H. Kim, Adv. Mater. Research, 275, 174 (2011).
  17. K. R. Trethewey and J. Chamberlain, Corros. Sci. Eng., 2nd ed. Longman Scientific & Technical, England (1995).
  18. A. J. Sedriks, Corrosion of stainless steels, A Wiley-Interscience Publication, New York (1996).
  19. X. G. Wang, D. Dumortier, and Y. Riquiier, Duplex Stainless Steel '91, p. 127, France (1991).
  20. V. Randle and G. Owen, Acta Mater., 54, 1777 (2006).
  21. P. Lin, G. Palumbo, U. Erb, and K. T. Aust, Scripta Metall. Mater., 33, 1387 (1995).
  22. G. Palumbo, K. T. Aust, E. M. Lehockey, U. Erb, and P. Lin, Scripta Mater., 38, 1685 (1998).
  23. Y. Pan, B. L. Adams, T. Olson, and N. Panayotou, Acta Mater., 44, 4685 (1996).
  24. M. Shimada, H. Kokawa, Z. J. Wang, Y. S. Sato, and I. Karibe, Acta Mater., 50, 2331 (2002).
  25. S. Kumar, B. S. Prasad, V. Kain, and J. Reddy, Corros. Sci., 70, 55 (2013).
  26. M. Kumar, W. E. King, and A. J. Schwartz, Acta Mater., 48, 2081 (2000).
  27. D. N. Wasnik, V. Kain, I. Samajdar, B. Verlinden, and P. K. De, Acta Mater., 50, 4587 (2002).
  28. P. M. Ahmedabadi, V. Kain, B. K. Dangi, and I. Samajdar, Corros. Sci., 66, 242 (2013).
  29. R. Jones and V. Randle, Mater. Sci. Eng A, 527, 4275 (2010).
  30. M. Michiuchi, H. Kokawa, Z. J. wang, Y. S. Sato, and K. Sakai, Acta Mater., 54, 5179 (2006).
  31. V. Randle, Acta Mater., 52, 4067 (2004).
  32. Y. Hyun, H. Kim, Corros. Sci. Tech., 12, 265 (2013).
  33. A. Telang, A. S. Gill, D. Tammana, X. Wen, M. Kumar, S. Teysseyre, S. R. Mannava, D. Qian, and V. K. Vasudevan, Mater. Sci. Eng A, 648, 280 (2015).
  34. O. Takakuwa and H. Soyama, Chemical Eng. Sci., 5, 62 (2015).
  35. I. Kauris and W. Gust, Fundamentals of grain and interface boundary diffusion, p. 275, Ziegler Press, Stuttgart, Germany (1988).
  36. JLe Coze, M. Biscondi, J. Levy, C. Goux, Mem. Sci. Rev. Metall, 70, 397 (1973).
  37. JLe Coze, M. Biscondi, Can. Metall. Q., 13, 59 (1974).
  38. M. Froment, J. Phys. Paris, 36, C4 (1975).
  39. X. R. Qian, Y. T. Chou, Philos. Mag. A, 45, 1075 (1982).
  40. P. H. Pumphrey, Special high angle boundaries, grain boundary structure and properties, p. 13, Academic Press, London (1976).
  41. G. Palumbo, K. T. Aust, Acta Metall. Mater., 38, 2343 (1990).
  42. P. Lin, G. Palumbo, U. Erb, K. T. Aust, Scripta Metall. Mater., 33, 1387 (1995).
  43. H. Kokawa, H. Shimada, Y. S. Sato, J. Mater., 52, 34 (2000).
  44. H. Kokawa, T. Koyanagawa, M. Shimada, Y. S. Sato, and T. Kuwana, Properties of complex inorganic solids, A. Meike ed., p. 1, Kluwer Academic Plenum, New York, (2000).
  45. R. V. Stickler, Mem. Sci. Rev. Metall., 60, 489 (1963).
  46. V. Cihal and I. Kacova, Corros. Sci., 10, 875 (1970).
  47. S. X. Li, Y. N. He, S. R. Yu, and P. Y. Zhang, Corros. Sci., 66, 211 (2013).
  48. ASTM A262, Standard practices for detecting susceptibility to intergranular attack in austenitic stainless steels, ASTM (2002).
  49. G. H. Aydogdu and M. K. Aydinol, Corros. Sci., 48, 3565 (2006).
  50. K. S. Lee, J. K. Lee, K. O. Song, and J. H. Park, Trans. Korean. Soc. Mech. Eng. A, 35, 453 (2011).
  51. J. K. Kim, Y. H. Kim, J. S. Lee, and K. Y. Kim, Corros. Sci., 52 ,1847 (2010).
  52. J. K. Kim, Y. H. Kim, B. H. Lee, and K. Y. Kim, Electrochim. Acta, 56, 1701 (2011).
  53. J. K. Kim, Y. H. Kim, S. H. Uhm, J. S. Lee, and K. Y. Kim, Corros. Sci., 51, 2716 (2009).
  54. J. K. Kim, B. J. Lee, B. H. Lee, Y. H. Kim, and K. Y. Kim, Scripta Mater., 61, 1133 (2009).
  55. B. Weiss and R. Stickler, Metall. Trans., 3, 851 (1972).
  56. H. Sahlaoui, K. Makhlouf, H. Sidhom, and J. Philibert, Mat. Sci. Eng. A, 372, 98 (2004).
  57. N. M. Alanazi, A. M. El-Sherik, S. H. Alamar, and S. Shen, Int. J. Electrochem. Sc., 8, 10350 (2013).
  58. X. Zhao, P. Munroe, D. Habibi, and Z. Xie, J. of Asian Ceramic Soc., 1, 86 (2013).
  59. T. Wang, J. Yu, and B. Dong, Surf. Coat. Techn., 200, 4777 (2006).
  60. W. Ye, Y. Li, and F. Wang, Electrochim. Acta, 51, 4426 (2006).

피인용 문헌

  1. Intergranular Corrosion Mechanism of Slightly-sensitized and UNSM-treated 316L Stainless Steel vol.15, pp.5, 2016,
  2. Effect of Ultrasonic Nano-Crystal Surface Modification (UNSM) on the Passivation Behavior of Aged 316L Stainless Steel vol.10, pp.7, 2017,