Synthesis and Properties of Polyurethane-Acrylate Top-Coating Agent

  • Son, Young-Joon (Department of Technology Business Policy Graduate School, Busan National University) ;
  • Lee, Dong Jin (Korea Institute of Footwear & Leather Technology) ;
  • Bae, Jong Woo (Korea Institute of Footwear & Leather Technology) ;
  • Lee, Jung Hee (Korea Institute of Footwear & Leather Technology)
  • Received : 2015.03.17
  • Accepted : 2015.04.13
  • Published : 2015.06.30


A series of polyurethane-acrylate hybrids were synthesized by 2-step emulsion polymerization of a variety of acrylate monomers such as 2-hydroxy ethyl methacrylate (HEMA), methyl methacrylate (MMA). Experiment was performed to improve stability and emulsibility of surface treatment agent, and it was found that the polyurethane-acrylate hybrids having an optimum composition (MMA : 20%, LA(EO)3-S : 3% and TDA-7 : 5%) was shown to be quite surface active in the solid contents. These results suggests that the optimal polyurethane-acrylate hybrids in this study have high potential as top coating agent, which may have high gloss and excellent properties.


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