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Characteristics and Preparation of Calcium Acetate from Butter Clam (Saxidomus purpuratus) Shell Powder by Response Surface Methodology

반응표면분석법을 이용한 개조개(Saxidomus purpuratus) 패각분말로부터 가용성 초산칼슘의 제조 및 특성

  • Lee, Hyun Ji (Department of Food and Nutrition, Institute of Marine Industry, Gyeongsang National University) ;
  • Jung, Nam Young (Nutrition Education Major, Graduate School of Education, Gyeongsang National University) ;
  • Park, Sung Hwan (Department of Food and Nutrition, Institute of Marine Industry, Gyeongsang National University) ;
  • Song, Sang Mok (Department of Food and Nutrition, Institute of Marine Industry, Gyeongsang National University) ;
  • Kang, Sang In (Department of Seafood Science and Technology, Institute of Marine Industry, Gyeongsang National University) ;
  • Kim, Jin-Soo (Department of Seafood Science and Technology, Institute of Marine Industry, Gyeongsang National University) ;
  • Heu, Min Soo (Department of Food and Nutrition, Institute of Marine Industry, Gyeongsang National University)
  • 이현지 (경상대학교 식품영양학과.해양산업연구소) ;
  • 정남영 (경상대학교 교육대학원 영양교육전공) ;
  • 박성환 (경상대학교 식품영양학과.해양산업연구소) ;
  • 송상목 (경상대학교 식품영양학과.해양산업연구소) ;
  • 강상인 (경상대학교 해양식품공학과.해양산업연구소) ;
  • 김진수 (경상대학교 해양식품공학과.해양산업연구소) ;
  • 허민수 (경상대학교 식품영양학과.해양산업연구소)
  • Received : 2015.02.02
  • Accepted : 2015.03.03
  • Published : 2015.06.30

Abstract

For effective utilization of butter clam shell as a natural calcium resource, the optimal conditions for preparation of calcium acetate (BCCA) with high solubility were determined using response surface methodology (RSM). The polynomial models developed by RSM for pH, solubility, and yield were highly effective in describing the relationships between factors (P<0.05). Increased molar ratio of calcined powder (BCCP) from butter clam shell led to reduction of solubility, yield, color values, and overall quality. Critical values of multiple response optimization to independent variables were 2.70 M and 1.05 M for acetic acid and BCCP, respectively. The actual values (pH 7.04, 93.0% for solubility and 267.5% for yield) under optimization conditions were similar to predicted values. White indices of BCCAs were in the range of 89.7~93.3. Therefore, color value was improved by calcination and organic acid treatment. Buffering capacity of BCCAs was strong at pH 4.88 to 4.92 upon addition of ~2 mL of 1 N HCl. Calcium content and solubility of BCCAs were 20.7~22.8 g/100 g and 97.2~99.6%, respectively. The patterns of fourier transform infrared spectrometer and X-ray diffractometer analyses from BCCA were identified as calcium acetate monohydrate, and microstructure by field emission scanning electron microscope showed an irregular form.

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