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Analysis of Trace Levels of Halonitromethanes (HNM) in Water using Headspace-SPME and GC-ECD

Headspace-SPME와 GC-ECD를 이용한 수중의 미량 Halonitromethane (HNM)류 분석

  • Received : 2015.05.18
  • Accepted : 2015.05.29
  • Published : 2015.05.31

Abstract

Halonitromethanes (HNMs) are one of the most toxic groups of disinfection by-products. Recently, various studies have been fulfilled. An automated headspace-solid phase microextraction (SPME) gas chromatography/electron capture detector (GC-ECD) technique was developed for routine analysis of 9 HNMs in water samples. The optimization of the method is discussed. The limits of detection (LOD) and limits of quantification (LOQ) range from 90 ng/L to 260 ng/L and from 270 ng/L to 840 ng/L for 9 HNMs, respectively. Matrix effects in tap water and sea water were investigated and it was shown that the method is suitable for the analysis of trace levels of HNMs, in a wide range of waters. The method developed in the present study has the advantage of being rapid, simple and sensitive.

Keywords

Halonitromethanes (HNMs);Disinfection By-products;Analysis;Solid Phase Microextraction (SPME);Gas Chromatography

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