Synthesis and Characterization of Phase Pure NiO Nanoparticles via the Combustion Route using Different Organic Fuels for Electrochemical Capacitor Applications

Srikesh, G.;Nesaraj, A. Samson

  • Received : 2014.10.17
  • Accepted : 2014.10.31
  • Published : 2015.03.31


Transition metal oxide nanocrystalline materials are playing major role in energy storage application in this scenario. Nickel oxide is one of the best antiferromagnetic materials which is used as electrodes in energy storage devices such as, fuel cells, batteries, electrochemical capacitors, etc. In this research work, nickel oxide nanoparticles were synthesized by combustion route in presence of organic fuels such as, glycine, glucose and and urea. The prepared nickel oxide nanoparticles were calcined at 600℃ for 3 h to get phase pure materials. The calcined nanoparticles were preliminarily characterized by XRD, particle size analysis, SEM and EDAX. To prepare nickel oxide electrode materials for application in supercapacitors, the calcined NiO nanoparticles were mixed with di-methyl-acetamide and few drops of nafion solution for 12 to 16 h. The above slurry was coated in the graphite sheet and dried at 50℃ for 2 to 4 h in a hot air oven to remove organic solvent. The dried sample was subjected to electrochemical studies, such as cyclic voltammetry, AC impedance analysis and chrono-coulometry studies in KOH electrolyte medium. From the above studies, it was found that nickel oxide nanoparticles prepared by combustion synthesis using glucose as a fuel exhibited resulted in low particle diameter (42.23 nm). All the nickel oxide electrodes have shown better good capacitance values suitable for electrochemical capacitor applications.


Nickel oxide nanoparticles;combustion route with different organic fuels;physical characterization;electrochemical studies;electrochemical capacitors


  1. X. Zhang, W. Shi, J. Zhu, W. Zhao, J. Ma, S. Mhaisalkar, T.L. Maria, Y. Yang, H. Zhang, H.H. Hng and Q. Yan, Nano Res., 3, 643 (2010).
  2. E. Frackowiak and F. Beguin, Carbon, 39, 937(2001).
  3. J.L. Liu, L.Z. Fan and X. Qu, Electrochimica Acta, 66, 302 (2012).
  4. K.O. Moura, R.J.S. Lima, C.B.R. Jesus, J.G.S. Duque and C.T. Meneses, Revista Mexicana de F'ιsica, S 58, 167 (2012).
  5. F. Davar, Z. Fereshteh and M.S. Niasari, J. Alloys and Compounds, 476, 797 (2009).
  6. S.A.E. Safty, M. Khairy, M. Ismael and H. Kawarada, Applied Catalysis B: Environmental, 123-124, 162 (2012).
  7. F. Lin, M. Montano, C. Tian, Y. Ji, D. Nordlund, T.C. Weng, R.G. Moore, D.T. Gillaspie, K.M. Jones, A.C. Dillon, R.M. Richards and C. Engtrakul, Solar Energy Materials and Solar Cells, 126, 206 (2014).
  8. B. Vidhyadharan, N.K.M. Zain, I.I. Misnon, R.A. Aziz, J. Ismail, M.M. Yusoff and R. Jose, J. Alloys and Compounds, 610, 143 (2014).
  9. A. Jena, N. Munichandraiah and S.A. Shivashankar, J. Power Sources, 237, 156 (2013).
  10. D.W. Wang, F. Li and H.M. Cheng, J. Power Sources, 185, 1563 (2008).
  11. L. Feng, Y. Zhu, H. Ding, C. Ni, J. Power Sources, 267, 430 (2014).
  12. S.K. Chang, Z. Zainal, K.B. Tan, N. A.Yusof, W.M.D. Wan Yusoff and S.R.S. Prabaharan, Current Appl. Phy., 12, 1421 (2012).
  13. R.R. Salunkhe, K. Jang, H. Yu, S. Yu, T. Ganesh, S.H. Han and H. Ahn, J. Alloys and Compounds, 509, 6677 (2011).
  14. J.Y. Choi and J.H. Choi, J. Indust. Engg. Chem., 16, 401 (2010).
  15. H.Y. Wu and H.W. Wang, Int. J. Electrochem. Sci., 7, 4405 (2012).
  16. W.H. Zhu, J.J. Ke, H.M. Yu and D.J. Zhang, J. Power Sources, 56, 75 (1995).
  17. B.T. Raut, S.G. Pawar, M.A. Chougule, Shaswati Sen and V.B. Patil, J Alloys and Compounds, 509, 9065 (2011).
  18. M. Hasan, M.Jamal and K.M. Razeeb, Electrochimica Acta, 60,193 (2012).
  19. J.P. Zheng and T.R. Jow, J. Electrochem. Soc., 142, L6 (1995).
  20. J.P. Zheng, P.J. Cygan and T.R. Jow, J. Electrochem. Soc. 142, 2699 (1995).
  21. C.C. Hu and Y. H. Huang, J. Electrochem. Soc. 146, 2495 (1999).
  22. Y. Zhang, G.Y. Li, Y. Lv, L.Z. Wang, A.Q. Zhang, Y.H. Song and B.L. Huang, J. Hydrogen Energy, 36, 11760 (2011).
  23. K.R. Prasad and N. Miura, Electrochem. Commun. 6, 1004 (2004).
  24. J. Yan, T. Wei, J. Cheng, Z. Fan and M. Zhang, Mater. Res. Bull. 45, 210 (2010).
  25. J. Xu, L. Gao, J. Cao, W. Wang and Z. Chen, Electrochimica Acta, 56, 732 (2010).
  26. Q. Yuanchun, Z. Yanbao and W. Zhishen, Mater. Chem. Phy., 110, 457 (2008).
  27. Y.Y. Ping, L.R. Sheng, H.K. Long, W.L. Ping, L.S. Qin and Z.W. Wen, Trans. Non ferrous Met. Soc. China, 17, 1334 (2007).
  28. K.C. Stella and A.S. Nesaraj, Iranian J. Materials Science & Engineering, 7, 36 (2010).
  29. G. Mattei, P. Mazzoldi, M.L. Post, D. Buso, M. Guglielmi and A. Martucci, J. Adv. Materials, 19, 561 (2007).
  30. M.W. Zhu, Z.J. Wang, Y.N. Chen and Z.D. Zhang, Surface & Coatings Tech. 216, 139 (2013).
  31. X.W. Lou, D. Deng, J.Y. Lee, J. Feng and L.A. Archer, Adv. Mater., 20, 258 (2008).
  32. Z.Z. Lin, F.L. Jiang, L. Chen, C.Y. Yue, D.Q. Yuan, A.J. Lan and M.C. Hong, Cryst. Growth Des. 7, 1712 (2007).
  33. Y. Wan and D. Zhao, Chem. Rev. 107, 2821 (2007).
  34. Q. Zhao, Z. Zhang, T. Dong and Y. Xie, J. Phys. Chem. B, 110, 15152 (2006).
  35. G.A. Seisenbaeva, M.P. Moloney, R. Tekoriute, A.H. Dessources, J.M. Nedelec, Y. K. Gun’ko, Vadim G. Kessler, Langmuir 26, 9809 (2010).
  36. Zhongli Wang, Ruixia Liu, Fengyu Zhao, Xiaojuan Liu, Minfeng Lv and Jian Meng, Langmuir, 26, 10135 (2010).
  37. A.Z. Sadek, H. Zheng, M. Breedon, V. Bansal, S.K. Bhargava, K. Latham, J. Zhu, L. Yu, Z. Hu, P.G. Spizzirri, W. Wlodarski and K. K. Zadeh, Langmuir, 25, 9545 (2009).
  38. D.B. Robinson, C.A.M. Wu, M.D. Ong, B.W. Jacobs and B.E. Pierson, Langmuir 26, 6797 (2010).
  39. T. Stimpfling and F. Leroux, Chem. Mater., 22, 974 (2010).
  40. D. Carriazo, F. Picó, M.C. Gutiérrez, F. Rubio, J.M. Rojo and F. D. Monte, J. Mater. Chem. 20, 773 (2010).
  41. K. Wang, Y. Wang, Y. Wang, E. Hosono and H. Zhou, J. Phys. Chem. C, 113, 1093 (2009).
  42. G.M. Suppes, B.A. Deore and M.S. Freund, Langmuir, 24, 1064 (2008).
  43. Q. Cheng, J. Tang, J. Ma, H. Zhang, N. Shinya and L.C. Qin, Carbon, 49, 2917 (2011).
  44. E.H. Liu, W. Li, J. Li, X.Y. Meng, R. Ding and S.T. Tan, Mater. Res. Bull., 44, 1122 (2009)
  45. M.D. Stoller and R.S. Ruoff, Energy Environ. Sci., 3, 1294 (2010)
  46. E. Kim, D. Son, T.G. Kim, J. Cho, B. Park, K.S. Ryu and S.H. Chang, Angew. Chem. Int. Ed., 43, 5987 (2004).
  47. X.W. Lou, D. Deng, J.Y. Lee and L.A. Archer, J. Mater. Chem., 18, 4397 (2008).