DOI QR코드

DOI QR Code

Electrosynthesis and Electrochemical Properties of Metal Oxide Nano Wire/ P-type Conductive Polymer Composite Film

  • Siadat, S.O. Ranaei
  • Received : 2015.05.26
  • Accepted : 2015.07.06
  • Published : 2015.09.30

Abstract

This study introduces a facile strategy to prepare metal oxide/conducting polymer nanocomposites that may have promising applications in energy storage devices. Ploy aniline/nano wire manganese dioxide (PANI/NwMnO2) was synthesized by cyclic voltammetry on glassy carbon electrode. Morphology and structure of the composite, pure PANI, MnO2 nanowires were fully characterized using XRD and SEM analysis. Electrochemical studies shows excellent synergistic effect between PANI and MnO2 nanowires which results in its capacitance increase and cycle stability against PANI electrode. Specific capacitances of PANI/NwMnO2 and PANI were 456 and 190 F/g respectively. The electrochemical performance of electrodes studied using cyclic voltammetry, Galvanostatic charge/discharge and impedance spectroscopy.

Keywords

super capacitors;nanowire;impedance;nanocomposite.

References

  1. Ehsani, A., et al., Poly ortho aminophenol/TiO 2 nanocomposite: electrosynthesis and characterization. Synthetic Metals, 2013. 165: p. 51-55. https://doi.org/10.1016/j.synthmet.2013.01.004
  2. Li, X., et al., In-situ polymerization of polyaniline on the surface of graphene oxide for high electrochemical capacitance. Thin Solid Films, 2015. 584: p. 348-352. https://doi.org/10.1016/j.tsf.2015.01.055
  3. Wang, H., et al., Effect of graphene oxide on the properties of its composite with polyaniline. ACS applied materials & interfaces, 2010. 2(3): p. 821-828. https://doi.org/10.1021/am900815k
  4. Nam, K.-W., et al., Pseudocapacitive properties of electrochemically prepared nickel oxides on 3-dimensional carbon nanotube film substrates. Journal of Power Sources, 2008. 182(2): p. 642-652. https://doi.org/10.1016/j.jpowsour.2008.03.090
  5. Hulicova-Jurcakova, D., et al., Graphitic carbon nanofibers synthesized by the chemical vapor deposition (CVD) method and their electrochemical performances in supercapacitors. Energy & Fuels, 2008. 22(6): p. 4139-4145. https://doi.org/10.1021/ef8004306
  6. Molina, J., et al., Electrochemical polymerisation of aniline on conducting textiles of polyester covered with polypyrrole/AQSA. European Polymer Journal, 2009. 45(4): p. 1302-1315. https://doi.org/10.1016/j.eurpolymj.2008.11.003
  7. Ehsani, A., M. Mahjani, and M. Jafarian, Electrosynthesis of poly ortho aminophenol films and nanoparticles:A comparative study. Synthetic Metals, 2012. 162(1): p. 199-204. https://doi.org/10.1016/j.synthmet.2011.11.032
  8. Long, J.W., A.L. Young, and D.R. Rolison, Spectroelectrochemical characterization of nanostructured, mesoporous manganese oxide in aqueous electrolytes. Journal of the Electrochemical Society, 2003. 150(9): p. A1161-A1165. https://doi.org/10.1149/1.1593651
  9. Reddy, R.N. and R.G. Reddy, Synthesis and electrochemical characterization of amorphous MnO 2 electrochemical capacitor electrode material. Journal of Power Sources, 2004. 132(1): p. 315-320. https://doi.org/10.1016/j.jpowsour.2003.12.054
  10. Hsieh, Y.-C., et al., Investigation on capacity fading of aqueous MnO 2· nH 2 O electrochemical capacitor. Journal of Power Sources, 2008. 177(2): p. 660-664. https://doi.org/10.1016/j.jpowsour.2007.11.026
  11. Sadeghinia, M., M. Rezaei, and E. Amini, Preparation of á-MnO 2 nanowires and its application in low temperature CO oxidation. Korean Journal of ChemicalEngineering, 2013. 30(11): p. 2012-2016.
  12. Lei, Z., Z. Chen, and X. Zhao, Growth of polyaniline on hollow carbon spheres for enhancing electrocapacitance. The Journal of Physical Chemistry C, 2010. 114(46): p.19867-19874. https://doi.org/10.1021/jp1084026
  13. Plesu, N., et al., Effect of temperature on the electrochemical synthesis and properties of polyaniline films. Journal of Non-Crystalline Solids, 2010. 356(20): p. 1081-1088. https://doi.org/10.1016/j.jnoncrysol.2010.01.011
  14. Conway, B.E., Electrochemical supercapacitors: scientific fundamentals and technological applications. 2013: Springer Science & Business Media.
  15. Ehsani, A., M. Mahjani, and M. Jafarian, An electrochemical study of the synthesis and properties of multi-walled carbon nanotube/poly ortho aminophenol composites. Synthetic Metals, 2011. 161(15): p. 1760-1765. https://doi.org/10.1016/j.synthmet.2011.06.020
  16. Dhand, C., et al., Recent advances in polyaniline based biosensors. Biosensors and Bioelectronics, 2011. 26(6): p. 2811-2821. https://doi.org/10.1016/j.bios.2010.10.017
  17. Patil, A., et al., Issue and challenges facing rechargeable thin film lithium batteries. Materials research bulletin, 2008. 43(8): p. 1913-1942. https://doi.org/10.1016/j.materresbull.2007.08.031
  18. de Heer, W.A., et al., Electron field emitters based on carbon nanotube films. Advanced Materials, 1997. 9(1): p. 87-89. https://doi.org/10.1002/adma.19970090122
  19. Rao, C.N.R., et al., Nanotubes. ChemPhysChem, 2001. 2(2): p. 78-105. https://doi.org/10.1002/1439-7641(20010216)2:2<78::AID-CPHC78>3.0.CO;2-7
  20. Liu, Z., et al., Organizing single-walled carbon nanotubes on gold using a wet chemical self-assembling technique. Langmuir, 2000. 16(8): p. 3569-3573. https://doi.org/10.1021/la9914110
  21. Shabani Shayeh, J., P. Norouzi, and M.R. Ganjali, Studying the supercapacitive behavior of a polyaniline/nano-structural manganese dioxide composite using fast Fourier transform continuous cyclic voltammetry. RSC Advances, 2015. 5(26): p. 20446-20452. https://doi.org/10.1039/C4RA16801A
  22. Simon, P. and Y. Gogotsi, Materials for electrochemical capacitors. Nature materials, 2008. 7(11): p. 845-854. https://doi.org/10.1038/nmat2297
  23. Ates, M., Review study of electrochemical impedance spectroscopy and equivalent electrical circuits of conducting polymers on carbon surfaces. Progress in Organic Coatings, 2011. 71(1): p. 1-10. https://doi.org/10.1016/j.porgcoat.2010.12.011
  24. Jurewicz, K., et al., Supercapacitors from nanotubes/polypyrrole composites. Chemical Physics Letters, 2001. 347(1): p. 36-40. https://doi.org/10.1016/S0009-2614(01)01037-5
  25. Hall, P.J., et al., Energy storage in electrochemical capacitors: designing functional materials to improve performance. Energy & Environmental Science, 2010. 3(9): p. 1238-1251. https://doi.org/10.1039/c0ee00004c
  26. Xia, K., et al., Hierarchical porous carbons with controlled micropores and mesopores for supercapacitor electrode materials. Carbon, 2008. 46(13): p. 1718-1726. https://doi.org/10.1016/j.carbon.2008.07.018
  27. Wu, F. and B. Xu, Progress on the application of carbon nanotubes in supercapacitors. New Carbon Materials, 2006. 21(2): p. 176-184.
  28. Zhao, D., et al., An electrochemical capacitor electrode based on porous carbon spheres hybrided with polyaniline and nanoscale ruthenium oxide. ACS applied materials & interfaces, 2012. 4(10): p. 5583-5589. https://doi.org/10.1021/am301484s
  29. Sun, Z. and X. Lu, A solid-state reaction route to anchoring Ni (OH) 2 nanoparticles on reducedgraphene oxide sheets for supercapacitors. Industrial & Engineering Chemistry Research, 2012. 51(30): p. 9973-9979. https://doi.org/10.1021/ie202706h
  30. Lefebvre, M., et al., Chemical synthesis, characterization, and electrochemical studies of poly (3, 4-ethylenedioxy-thiophene)/poly (styrene-4-sulfonate) composites. Chemistry of materials, 1999. 11(2): p. 262-268. https://doi.org/10.1021/cm9804618
  31. Xu, D., et al., Fabrication of free-standing hierarchical carbon nanofiber/graphene oxide/polyaniline films for supercapacitors. ACS applied materials & interfaces, 2013. 6(1): p. 200-209.
  32. Zhang, X., et al., Investigation of a Branchlike MoO3/Polypyrrole Hybrid with Enhanced Electrochemical Performance Used as an Electrode in Supercapacitors. ACS applied materials & interfaces, 2014. 6(2): p. 1125-1130. https://doi.org/10.1021/am404724u

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