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Investigation of Furfural Yields of Liquid Hydrolyzate during Dilute Acid Pretreatment Process on Quercus Mongolica using Response Surface Methodology

신갈나무 약산 전처리 공정 중 반응표면분석법을 이용한 액상 가수분해물의 furfural 수율 탐색

  • Received : 2015.07.27
  • Accepted : 2015.09.22
  • Published : 2016.01.25

Abstract

In this study, furfural, which is one of the value-added chemicals, was produced from the hydrolyzate of Quercus mongolica using dilute acid pretreatment, and the optimal pretreatment condition was determined by Response Surface Methodology (RSM) to obtain high yield of furfural. Based on Central Composite Design, the pretreatment experiment was designed with parameters such as reaction temperature ($X_1$), acid concentration ($X_2$), and reaction time ($X_3$) as independent variables, while dependent variable was furfural concentration (Y), and furfural yield (Z) was shown as percentage of Y per a dry weight basis. According to results of RSM, it was confirmed that reaction temperature ($X_1$) was the most influence factor and reaction temperature ($X_1$)-acid concentration ($X_2$) was the most significant interaction factor on furfural yield. Also, the optimal condition for the highest furfural yield was predicted at reaction temperature of $184^{\circ}C$, acid concentration of 1.17%, and reaction time of 5 min by RSM, and expected maximum yield of furfural was 6.37%. Experimentally, the maximum yield of furfural produced at above optimal condition was 6.21%, and it was considerably similar with the predicted value, and therefore the model for furfural production from the hydrolyzate of Quercus mongolica during dilute acid pretreatment could be built using RSM.

Keywords

furfural;dilute acid pretreatment;response surface methodology;biorefinery;Quercus mongolica

References

  1. Agirrezabal-Telleria, I., Gandarias, I., Arias, P. 2013. Production of furfural from pentosan-rich biomass: analysis of process parameters during simultaneous furfural stripping. Bioresource technology 143(1): 258-264. https://doi.org/10.1016/j.biortech.2013.05.082
  2. Borges da Silva, E.B., Zabkova, M., Araujo, J., Cateto, C., Barreiro, M., Belgacem, M., Rodrigues, A. 2009. An integrated process to produce vanillin and lignin-based polyurethanes from Kraft lignin. Chemical Engineering Research and Design 87(9): 1276-1292. https://doi.org/10.1016/j.cherd.2009.05.008
  3. Bozell, J.J., Petersen, G.R. 2010. Technology development for the production of biobased products from biorefinery carbohydrates-the US Department of Energy's "top 10" revisited. Green Chemistry 12(4): 539-554. https://doi.org/10.1039/b922014c
  4. Cai, C.M., Zhang, T., Kumar, R., Wyman, C.E. 2014. Integrated furfural production as a renewable fuel and chemical platform from lignocellulosic biomass. Journal of Chemical Technology and Biotechnology 89(1): 2-10. https://doi.org/10.1002/jctb.4168
  5. Dussan, K., Girisuta, B., Haverty, D., Leahy, J., Hayes, M. 2013. Kinetics of levulinic acid and furfural production from Miscanthus$\chi$giganteus. Bioresource technology 149(1): 216-224. https://doi.org/10.1016/j.biortech.2013.09.006
  6. Gallezot, P. 2012. Conversion of biomass to selected chemical products. Chemical Society Reviews 41(4): 1538-1558. https://doi.org/10.1039/C1CS15147A
  7. Gonzalez-Delgado, A.-D., Kafarov, V. 2011. Microalgae based biorefinery: Issues to consider. CT&F-Ciencia, Tecnologia $\gamma$ Futuro 4(4): 5-22.
  8. Jeong, G.-T., 2014. Production of chemical intermediate furfural from renewable biomass Miscanthus Straw. Korean Chem. Eng. Res. 52(4): 492-496. https://doi.org/10.9713/kcer.2014.52.4.492
  9. GyeongJin, S., SoYeon, J., HongJoo, L., JaeWon, L. 2015. Furfural production and recovery by two-stage acid treatment of lignocellulosic biomass. Journal of the Korean Wood Science and Technology 43(1): 76-85. https://doi.org/10.5658/WOOD.2015.43.1.76
  10. Jeong, G.T. 2014. Production of chemical intermediate furfural from renewable biomass Miscanthus straw. Korean Chem. Eng. Res. 52(4): 492-496. https://doi.org/10.9713/kcer.2014.52.4.492
  11. John, R.P., Anisha, G., Nampoothiri, K.M., Pandey, A. 2011. Micro and macroalgal biomass: a renewable source for bioethanol. Bioresource Technology 102(1): 186-193. https://doi.org/10.1016/j.biortech.2010.06.139
  12. Karinen, R., Vilonen, K., Niemela, M. 2011. Biorefining: heterogeneously catalyzed reactions of carbohydrates for the production of furfural and hydroxymethylfurfural. ChemSusChem 4(8): 1002-1016. https://doi.org/10.1002/cssc.201000375
  13. Kim, H.Y., Lee, J.W., Jeffries, T.W., Choi, I.G. 2011. Evaluation of oxalic acid pretreatment condition using response surface method for producing bio-ethanol from Yellow poplar (Liriodendron tulipifera) by simultaneous saccharification and fermentation. Journal of The Korean Wood Science and Technology 39(1): 75-85. https://doi.org/10.5658/WOOD.2011.39.1.75
  14. Kumar, P., Barrett, D.M., Delwiche, M.J., Stroeve, P. 2009. Methods for pretreatment of lignocellulosic biomass for efficient hydrolysis and biofuel production. Industrial & Engineering Chemistry Research 48(8): 3713-3729. https://doi.org/10.1021/ie801542g
  15. Lange, J.P., van der Heide, E., van Buijtenen, J., Price, R. 2012. Furfural-a promising platform for lignocellulosic biofuels. ChemSusChem 5(1): 150-166. https://doi.org/10.1002/cssc.201100648
  16. Lee, J.W., Rodrigues, R.C., Kim, H.J., Choi, I.-G., Jeffries, T.W. 2010. The roles of xylan and lignin in oxalic acid pretreated corncob during separate enzymatic hydrolysis and ethanol fermentation. Bioresource technology 101(12): 4379-4385. https://doi.org/10.1016/j.biortech.2009.12.112
  17. Lee, Y.J., Lim, J.L., Lee, K.H., Heo, T.Y. 2012. Optimization of coagulation conditions for the drinking water treatment using response surface method (RSM). Korean Society of Water Science and Technology 20(5): 81-89.
  18. Mandalika, A., Runge, T. 2012. Enabling integrated biorefineries through high-yield conversion of fractionated pentosans into furfural. Green Chemistry 14(11): 3175-3184. https://doi.org/10.1039/c2gc35759c
  19. Mamman, A.S., Lee, J.M., Kim, Y.C., Hwang, I.T., Park, N.J., Hwang, Y.K., Chang, J.S., Hwang, J.S. 2008. Furfural: Hemicellulose/xylose derived biochemical. Biofuels, Bioproducts and Biorefining 2(5): 438-454. https://doi.org/10.1002/bbb.95
  20. Mood, S.H., Golfeshan, A.H., Tabatabaei, M., Jouzani, G.S., Najafi, G.H., Gholami, M., Ardjmand, M. 2013. Lignocellulosic biomass to bioethanol, a comprehensive review with a focus on pretreatment. Renewable and Sustainable Energy Reviews 27(1): 77-93. https://doi.org/10.1016/j.rser.2013.06.033
  21. Mosier, N., Wyman, C., Dale, B., Elander, R., Lee, Y., Holtzapple, M., Ladisch, M. 2005. Features of promising technologies for pretreatment of lignocellulosic biomass. Bioresource technology 96(6): 673-686. https://doi.org/10.1016/j.biortech.2004.06.025
  22. Palmqvist, E., Hahn-Hagerdal, B. 2000. Fermentation of lignocellulosic hydrolysates. II: inhibitors and mechanisms of inhibition. Bioresource technology 74(1): 25-33. https://doi.org/10.1016/S0960-8524(99)00161-3
  23. Pan, X., Gilkes, N., Kadla, J., Pye, K., Saka, S., Gregg, D., Ehara, K., Xie, D., Lam, D., Saddler, J. 2006. Bioconversion of hybrid poplar to ethanol and co-products using an organosolv fractionation process: optimization of process yields. Biotechnology and bioengineering 94(5): 851-861. https://doi.org/10.1002/bit.20905
  24. Pettersen, R.C. 1984. The chemical composition of wood. The chemistry of solid wood 207(1): 57-126. https://doi.org/10.1021/ba-1984-0207.ch002
  25. Raman, J.K., Gnansounou, E. 2015. Furfural production from empty fruit bunch-A biorefinery approach. Industrial Crops and Products 69(1): 371-377. https://doi.org/10.1016/j.indcrop.2015.02.063
  26. Sluiter, A., Hames, B., Ruiz, R., Scarlata, C., Sluiter, J., Templeton, D., Crocker, D. 2008. In Laboratory Analytical Procedure No. TP-510-42618. NREL, Golden, CO.
  27. Werpy, T., Petersen, G., Aden, A., Bozell, J., Holladay, J., White, J., Manheim, A., Eliot, D., Lasure, L., Jones, S. 2004. Top value added chemicals from biomass. Volume 1-Results of screening for potential candidates from sugars and synthesis gas. DTIC Document.
  28. Yan, K., Wu, G., Lafleur, T., Jarvis, C. 2014. Production, properties and catalytic hydrogenation of furfural to fuel additives and value- added chemicals. Renewable and Sustainable Energy Reviews 38(1): 663-676. https://doi.org/10.1016/j.rser.2014.07.003

Cited by

  1. Energy Efficiency of Fluidized Bed Drying for Wood Particles vol.44, pp.6, 2016, https://doi.org/10.5658/WOOD.2016.44.6.821

Acknowledgement

Supported by : 산림청