Role of Different Oxide to Fuel Ratios in Solution Combustion Synthesis of SnO2 Nanoparticles

Chavan, Archana U.;Kim, Ji-Hye;Im, Ha-Ni;Song, Sun-Ju

  • Received : 2015.11.25
  • Accepted : 2016.01.13
  • Published : 2016.01.31


Tin oxide ($SnO_2$) nanoparticles have been synthesized by solution combustion method using citric acid as a fuel. The oxide to fuel ratio has been varied to obtain ultrafine nanoparticles with better surface area; such particles will be useful in many applications. With this synthesis method, spherical particles are formed having a particle size in the range of 11-30 nm and BET surface area of ~ $24m^2/g$. The degree of agglomeration of $SnO_2$ nanoparticles has been calculated.


$SnO_2$;Nanoparticle;Combustion synthesis


  1. Y. Liu, Y. Jiao, Z. Zhang, F. Qu, A. Umar, and X. Wu, "Hierarchical $SnO_2$ Nanostructures Made of Intermingled Ultrathin Nanosheets for Environmental Remediation, Smart Gas Sensor, and Supercapacitor Applications," ACS Appl. Mater. Interface, 6 2174-84 (2014).
  2. Q. Zhao, D. Ju, X. Deng, J. Huang, B. Cao, and X. Xu, "Morphology-Modulation of $SnO_2$ Hierarchical Architectures by Zn Doping for Glycol Gas Sensing and Photocatalytic Applications," Sci. Rep., 7874 1-5 (2015).
  3. L. C. Nehru and C. Sanjeeviraja, "Rapid Synthesis of Nanocrystalline $SnO_2$ by a Microwave-Assisted Combustion Method," J. Adv. Ceram., 3 [3] 171-76 (2014).
  4. Y. Han, X. Wu, G. Shen, B. Dierre, L. Gong, F. Qu, Y. Bando, T. Sekiguchi, F. Filippo, and D. Golberg, "Solution Growth and Cathodoluminescence of Novel $SnO_2$ Core-Shell Homogeneous Microspheres," J. Phys. Chem. C., 114 8235-40 (2010).
  5. H. Taib and C. C. Sorrell, "Preparation of Tin Oxide," J. Aust. Ceram. Soc., 43 [1] 56-61 (2007).
  6. L. M. Sikhwivhilu, S. K. Pillai, and T. K. Hillie, "Influence of Citric Acid on $SnO_2$ Nanoparticles Sythesized by Wet Chemical Processes," J. Nanosci. Nanotech., 11 [6] 4988-94 (2011).
  7. Y. Cui, A. Yu, H. Pan, X. Zhou, and X. Ding "Catalytic Outgrowth of $SnO_2$ Nanorods from ZnO-$SnO_2$ Nanoparticles Microsphere Core: Combustion Synthesis and Gas-Sensing Properties," Cryst. Eng. Comm., 14 7355-59 (2012).
  8. A. Ayeshamariam, V. S. Vidhya, T. Sivakumar, R. Mahendran, R. Perumalsamy, N. Sethupathy, and M. Jayachandran "Nanoparticles of $In_2O_3$/$SnO_2$ (90/10) and (80/20) at Two Different Proportions and Its Properties," Open J. Met., 3 1-7 (2013).
  9. M. Bhagwat, P. Shah, and V. Ramaswamy, "Synthesis of Nanocrystalline $SnO_2$ Powder by Amorphous Citrate Route," Mater. Lett., 57 1604-11 (2003).
  10. S. Banerjee, A. Bumajdad, and P. S. Devi "Nanoparticles of Antimony Doped Tin Dioxide as a Liquid Petroleum Gas Sensor: Effect of Size on Sensitivity," Nanotechnol., 22 [275506] 1-8 (2011).
  11. L. B. Fraigi, D. G. Lamas, and N. E. Wals e de Reca, "Comparison between Two Combustion Routes for the Synthesis of Nanocrystalline $SnO_2$ Powders," Mater. Lett., 47 262-66 (2001).
  12. A. Bhattacharjee and M. Ahmaruzzaman, "A Green Approach for the Synthesis of $SnO_2$ Nanoparticles and its Application in the Reduction of p-nitrophenol," Mater. Lett., 157 260-64 (2015).
  13. K. S. W. Sing, D. H. Everett, R. A. W. Haul, L. Moscou, R. A. Pierotti, J. Rouquerol, and T. Siemieniewska, "REPORTING PHYSISORPTION DATA FOR GAS/SOLID SYSTEMS with Special Reference to the Determination of Surface Area and Porosity," Pure Appl. Chem., 57 603-19 (1985).
  14. S. A. Feyzabad, Y. Mortazavi, A. A. Khodadadi, and S. Hemmati, "$Sm_2O_3$ Doped-$SnO_2$ Nanoparticles, Very Selective and Sensitive to Volatile Organic Compounds," Sens. Actuators, B, 181 910-18 (2013).


Supported by : Chonnam National University