- Volume 27 Issue 1
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Effects of Solubility of SO2 Gas on Continuous Bunsen Reaction using HIx Solution
HIx 용액을 이용한 연속식 분젠 반응에 미치는 SO2용해도의 영향
- KIM, JONGSEOK ;
- PARK, CHUSIK ;
- KANG, KYOUNGSOO ;
- JEONG, SEONGUK ;
- CHO, WON CHUL ;
- KIM, YOUNG HO ;
- BAE, KI KWANG
- Received : 2016.02.01
- Accepted : 2016.02.28
- Published : 2016.02.29
The Sulfur-Iodine thermochemical hydrogen production process (SI process) consists of the Bunsen reaction section, the
Hydrogen production;SI process;Bunsen reaction;HIx solution;Continuous reaction;Pressurized reaction
- J. E. Funk, "Thermochemical Hydrogen Production: Past and Present", Int. J. Hydrogen Energy, Vol. 26, 2001, p. 185. https://doi.org/10.1016/S0360-3199(00)00062-8
- J. E. Funk, R. M. Reinstrom, "Energy Requirements in the Production of Hydrogen from Water", Ind. Eng. Chem. Proc. Des. Develop., Vol. 5, No. 3, 1966, p. 366. https://doi.org/10.1021/i360020a017
- S. Kasahara, G. J. Hawng, H. Nakajima, H. S. Choi, K. Onuki, and M. Nomura, "Effects of process parameters of the IS process on total thermal efficiency to produce hydrogen from water", J. Chem. Eng. Japan, Vol. 36, No. 7, 2003, p. 887. https://doi.org/10.1252/jcej.36.887
- S. Kasahara, S. Kubo, K. Onuki, and M. Nomura, "Thermal efficiency evaluation of HI synthesis/ concentration procedures in the thermochemical water splitting IS process", Int. J. Hydrogen Energy, Vol. 29, No. 6, 2004, p. 579. https://doi.org/10.1016/j.ijhydene.2003.08.005
- S. Goldstein. J. M. Borgard, and X. Vitart, "Upper bond and best estimate of the efficiency of the iodine sulfur cycle", Int. J. Hydrogen Energy, Vol. 30, No. 6, 2005, p. 619. https://doi.org/10.1016/j.ijhydene.2004.06.005
- S. Kubo, H. Nakajima, S. Kasahara, S. Higashi, T. Masaki, H. Abe, and K Onuki, "A Demonstration Study on a Closed Cycle Hydrogen Production by the Thermochemical Water-Splitting Iodine-Sulfur Process", Nucl. Eng. Des., Vol. 233, 2004, p. 347. https://doi.org/10.1016/j.nucengdes.2004.08.025
- A. Giaconia, G. Caputo, A. Ceroli, M. Diamanti, V. Barbarossa, P. Tarquini, and S. Sau, "Experimental study of two phase separation in the Bunsen section of the sulfur-iodine thermochemical cycle", Int. J. Hydrogen Energy, Vol. 32, No. 5, 2007, p. 531. https://doi.org/10.1016/j.ijhydene.2006.08.015
- J. H. Norman, G. E. Bensenbruch, L. C. Brown, D. R. O'Keefe, and C. L. Allen, "Thermochemical water-splitting cycle: Bench scale investigations, and process engineering", GA-A16713, 1982.
- N. Sakaba, S. Kasahara, K. Onuki, and K. Kunitomi, "Conceptual design of hydrogen production system with thermochemical water-splitting iodine-sulphur process utilizing heat from the high-temperature gas-cooled reactor HTTR", Int. J. Hydrogen Energy, Vol. 32, No. 17, 2007, p. 4160. https://doi.org/10.1016/j.ijhydene.2007.06.005
K. Y. Lee, H. G. Kim, K. D. Jeong, and C. S. Kim, "
$SO_2/O_2$Separation Process with EMIm[ $EtSO_4$] in SI cycle for the Hydrogen Production by Water splitting", Trans. of the Korean Hydrogen and New Energy Society, Vol 22, No. 1, 2011, p. 13.
K. Y. Lee, K. H. Song, K. S. Yoo, H. G. Kim, K. D. Jeong, and C. S. Kim, "
$SO_2/O_2$Separation with [DMIm] $MeSO_4$In IS Cycle", Trans. of the Korean Hydrogen and New Energy Society, Vol. 19, No. 1, 2008, p. 49.
T. H. Kim, C. H. Shin, O. S. Joo, and K. D. Jeong, "
$SO_3$Decomposition Catalyst in SI cycle to Produce Hydrogen", Trans. of the Korean Hydrogen and New Energy Society, Vol. 22. No. 1, 2011, p. 21.
- P. Zhang, S. Z. Chen, L. J. Wang, T. Y. Yao, and J. M. Xu, "Study on a lab-scale hydrogen production by closed cycle thermo-chemical iodine-sulfur process", Int. J. Hydrogen Energy, Vol. 35, No. 19, 2010, p. 10166. https://doi.org/10.1016/j.ijhydene.2010.07.150
- W. C. Cho, C. S. Park, K. S. Kang, C. H. Kim and K. K. Bae, "Conceptual design of sulfur-iodine hydrogen production cycle of Korea Institute of Energy Research", Nucl. Eng. Des., Vol. 239, No. 3, 2009, p. 501. https://doi.org/10.1016/j.nucengdes.2008.11.017
M. B. Richards, A. S. Shenoy, L. C. Brown, R. T. Buckingham, E. A. Harvego, K. L. Peddicord, S. M. M. Reza, and J. P. Coupey, "
$H_2$-MHR Pre-Conceptual Design Report: SI-Based Plant; $H_2$-MHR Pre-Conceptual Design Report: HTE-Based Plant", GA-A25401, 2006.
H. S. Kim, D. W. Hong, S. J. Han, Y. H. Kim, C. S. Park, and K. K Bae, "The Phase Separation Characteristics of Bunsen Reaction with
$HI_x$solution in Sulfur-Iodine Hydrogen Production Process", Trans. of the Korean Hydrogen and New Energy Society, Vol. 21, No. 6, 2010, p. 479.
S. J. Han, H. S. Kim, B. T. Ahn, Y. H. Kim. C. S. Park, K. K. Bae, and J. G. Lee, "The Effect of
$SO_2-O_2$Mixture Gas on Phase Separation Composition of Bunsen Reaction with $HI_x$solution", Trans, of the Korean Hydrogen and New Energy Society, Vol. 23, No. 5, 2012, p. 421. https://doi.org/10.7316/KHNES.2012.23.5.421
- H. S. Kim, Y. H. Kim, S. J. Han, C. S. Park, K. K. Bae, and J. G. Lee, "Continuous Bunsen reaction and simultaneous separation using a counter-current flow reactor for the sulfur-iodine hydrogen production process", Int. J. Hydrogen Energy, Vol. 38, No. 14, 2013, p. 619.
- L. C. Brown, G. E. Bensenbruch, R. D. Lentsch, K. R. Schultz, J. F. Funk, P. S. Pickard, A. C. Marshall, and S. K. Showalter, "High efficiency generation of hydrogen furls using nuclear power", GA-A 24285, 2003.
- W. Henry, "Experiments on the quantity of gases absorbed by water, at different temperatures, and under different pressures". Phil. Trans. R. Soc. Lond., Vol 93, 1803, p. 29. https://doi.org/10.1098/rstl.1803.0004
- G. W. Greenwood, "The Solubility of Gas Bubbles", The J. Material Science, Vol. 4, No. 4, 1969, p. 320. https://doi.org/10.1007/BF00550401
S. D. Hong, C. H. Kim, J. G. Kim, S. H. Lee, K. K. Bae, and K. J. Hwang, "HI Concentration from
$HI_x$(HI- $H_2O-I_2$) Solution for the Thermochemical Water-Splitting IS process by Electro-Electrodialysis", J. Ind. Eng. Chem, Vol. 12, No. 4, 2006, p. 566.
Supported by : 한국연구재단, 한국에너지기술연구원, 한국에너지기술평가원(KETEP)