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Synthesis and Characterization of New Push-Pull Chromophores Containing BF2-Azopyrrole Derivatives

Ko, HayeMin

  • Received : 2015.11.06
  • Accepted : 2015.11.12
  • Published : 2016.02.20

Abstract

Novel push-pull chromophores containing 5’-(4-(bis(9,9-dimethyl-9H-fluoren-2-yl)aniline (bisDMFA) as a donor and phenylazo-methylpyrrolyl-boron difluoride (PhAPy-BF2) as an acceptor were designed and synthesized by the Knoevenagel condensation reaction for organic solar cells. Various electron withdrawing moieties were effectively introduced using 2,4-dimethyl-1H-pyrrole to afford new asymmetric BF2-azopyrrole molecules that were characterized by UV-vis spectroscopy and cyclic voltammetry measurements.

Keywords

Organic solar cell;Asymmetric BF2-azopyrrole molecules

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