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Process Technologies of Reforming, Upgrading and Purification of Anaerobic Digestion Gas for Fuel Cells

연료전지에의 적용을 위한 혐기성 소화가스의 정제, 고질화 및 메탄개질 기술

  • Received : 2016.03.17
  • Accepted : 2016.04.30
  • Published : 2016.04.30

Abstract

Biogas is a renewable fuel from anaerobic digestion of organic matters such as sewage sludge, manure and food waste. Raw biogas consists mainly of methane, carbon dioxide, hydrogen sulfide, and water. Biogas may also contain other impurities such as siloxanes, halogenated hydrocarbons, aromatic hydrocarbons. Efficient power technologies such as fuel cell demand ultra-low concentration of containments in the biogas feed, imposing stringent requirements on fuel purification technology. Biogas is upgraded from pressure swing adsorption after biogas purification process which consists of water, $H_2S$ and siloxane removal. A polymer electrolyte membrane fuel cell power plant is designed to operate on reformate produced from upgraded biogas by steam reformer.

Keywords

Anaerobic digestion gas;Purification;Upgrading;Methane Reformimg;Fuel Cell

References

  1. JongGyu Lee, JaeHo Jun, KyuHo Park, DooSung Choi, JaeYoung Park, " Anaerobic Digester Gas Purification for the Fuel Gas of the Fuel Cell", Trans. of the Korean Hydrogen and New Energy Society, Vol. 18, No. 2, 2007, p.164.
  2. Young-Kwan Lim, Joung-Min Lee, and Choong-Sub Jung, "The Status of Biogas as Renewable Energy", Appl. Chem. Eng., Vol. 23, No. 2, 2012, p. 125.
  3. Kwang Seok Oh, Kyo Sung Lee, Tae Bum Yoon, Ki Dong Kim, and Young Sam Oh, "Biogas as a Transport Fuel : Cleaning & Upgrading Technology", KIC News, Vol. 16, No. 2, 2013, p. 49.
  4. N. de Arespacochaga, C. Valderrama, C. Mesa, L. Bouchy, J.L. Cortina, " Biogas deep clean-up based on adsorption technologies for Solid Oxide Fuel Cell applications" Chemical Engineering Journal Vol. 255, No. 1, 2014, p. 593. https://doi.org/10.1016/j.cej.2014.06.072
  5. N. de Arespacochaga, C. Valderrama, C. Peregrina, C. Mesa, L. Bouchy, J.L. Cortina, "Evaluation of a pilot-scale sewage biogas powered 2.8 kWe Solid Oxide", Journal of Power Sources, Vol. 300, 2015, p. 325. https://doi.org/10.1016/j.jpowsour.2015.09.086
  6. Roberto Bove, Piero Lunghi, "Experimental comparison of MCFC performance using three different biogas types and methane" Journal of Power Sources, Vol. 145, 2005, p. 588. https://doi.org/10.1016/j.jpowsour.2005.01.069
  7. N. de Arespacochaga, C. Valderrama, C. Peregrina, A. Hornero, L. Bouchy, J.L. Cortina, "On-site cogenerationwith sewage biogas via high-temperature fuel cells: Benchmarking against other options based on industrial-scale data", Fuel Processing Technology, Vol. 138, 2015, p. 654. https://doi.org/10.1016/j.fuproc.2015.07.006
  8. V. Scholz and J. Ellner, "Use of Biogas in Fuel Cells - Current R&D "Journal of Sustainable Energy & Environment Special Issue, 2011, p. 11.
  9. Wojciech M. Budzianowski, Izabela Chasiak, "The expansion of biogas fuelled power plants in Germany during the 2001-2010 decade: Main sustainable conclusions for Poland", Journal of Power Technologies, Vol. 91, No. 2, 2011, p. 102.
  10. Ben Messenger, "Trigeneration Project Using Landfill Gas Powered Fuel Cells", https://wastemanagement- world.com/a/trigeneration-project-us ing-landfill-gas-powered-fuel-cells
  11. D. Thimsen, "Assessment of Fuel Gas Cleanup Systems for Waste Gas Fueled Power Generation" EPRI(Electric Power Research Institute), 2006.
  12. D. Papadias, S. Ahmed and Kumar, R. "Biogas Impurities and Cleanup for Fuel Cells: A Technical and Economic Analysis for a Molten Carbonate Fuel Cell System", 2012 Fuel Cell Seminar & Exposition.
  13. Mohammad Farooque, Anthony Leo, Anthony Rauseo and Jin-Yun Wang, 2015, "Efficient and ultra-clean use of biogas in the fuel cell - the DFC experience", Energy, Sustainability and Society, 5:11.
  14. S. Rasi, J. Lantela, J. Rintala, "Trace compounds affecting biogas energy utilisation - A review" Energy Conversion and Management, Vol. 52, 2011, p. 3369. https://doi.org/10.1016/j.enconman.2011.07.005
  15. D. D. Papadias, S. Ahmed, R. Kumar, "Fuel quality issues with biogas energy-An economic analysis for a stationary fuel cell system", Energy, Vol, 44, 2012, p. 257. https://doi.org/10.1016/j.energy.2012.06.031
  16. Mona Arnold, "Reduction and monitoring of biogas trace compounds", http://www.vtt.fi/inf/pdf/tiedotteet/2009/T2496.pdf
  17. K. Haga, S. Adachi, Y. hiratori, K. Itoh, K. Sasaki, "Poisoning of SOFC anodes by various fuel impurities", Solid State Ionics, Vol. 179, 2008, p. 1427. https://doi.org/10.1016/j.ssi.2008.02.062
  18. N. Abatzoglou, S. Boivin, "A review of biogas purification processes" Biofuels, Bioprod. Bioref. Vol. 3, 2009, p. 42.
  19. Laura Bailon Allegue, Jorgen Hinge, "Biogas upgrading Evaluation of methods for H2S removal", Danish Technogical Institute, 2014.
  20. Alptekin, G., Jayaraman, A. Schaefer, M. "Sulfatrap Sorbents for Effective Sulfur Removal for Fuel Cells: Dimethyl Sulfide, Mercaptan and COS Adsorption", AIChE 2014 Annual Meeting, Atlanta, GA, November 18, 2014.
  21. P. Gislon, S. Galli, G. Monteleone, "Siloxanes removal from biogas by high surface area adsorbents", Waste Management, Vol. 33, 2013, p. 2687. https://doi.org/10.1016/j.wasman.2013.08.023
  22. Alba Cabrera-Codony, Miguel A. Montes-Moran, Manuel Sanchez-Polo, Maria J. Martin, and Rafael Gonzalez-Olmos, "Biogas Upgrading: Optimal Activated Carbon Properties for Siloxane Removal", Environ. Sci. Technol. Vol. 48, 2014, p. 7187. https://doi.org/10.1021/es501274a
  23. Sangchul Nam, Wan Namkoong, Jeong-Hee Kang, Jin-Kyu Park, Namhoon Lee, "Adsorption characteristics of siloxanes in landfill gas by the adsorption equilibrium test", Waste Management, Vol. 33, 2013, p. 2091. https://doi.org/10.1016/j.wasman.2013.03.024

Cited by

  1. Analysis of cause of engine failure during power generation using biogas in sewage treatment plant vol.25, pp.4, 2016, https://doi.org/10.5855/ENERGY.2016.25.4.013

Acknowledgement

Supported by : 한국에너지기술평가원