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Performance of membrane filtration in the removal of iron and manganese from Malaysia's groundwater

  • Kasim, Norherdawati ;
  • Mohammad, Abdul Wahab ;
  • Abdullah, Siti Rozaimah Sheikh
  • Received : 2015.08.03
  • Accepted : 2016.03.22
  • Published : 2016.07.25

Abstract

The aim of this research was to investigate the ability of nanofiltration (NF) and ultrafiltration (UF) membranes as a filtration unit for groundwater treatment for drinking water resources. Commercial membranes denoted as TS40, TFC-SR3 and GHSP were used to study the performance based on rejections and fluxes. The investigation has been conducted using natural groundwater obtained from a deep tube well with initial concentration of iron (Fe) and manganese (Mn) at 7.15 mg/L and 0.87 mg/L, respectively. Experimental results showed that NF membranes exhibited higher fluxes than UF membrane with pure water permeability at 4.68, 3.99 and $3.15L.m^{-2}.h^{-1}.bar^{-1}$, respectively. For metal rejection, these membranes have performed higher removal on Fe with TS40, TFC-SR3 and GHSP membranes having more than 82%, 92% and 86% respectively. Whereas, removal on Mn only achieved up to 60%, 80% and 30%, for TS40, TFC-SR3 and GHSP membranes respectively. In order to achieve drinking water standard, the membranes were efficient in removing Fe ion at 1 and 2 bar in contrast with Mn ion at 4 and 5 bar. Higher rejection of Fe and Mn were achieved when pH of feed solution was increased to more than 7 as TFC-SR3 membrane was negatively charged in basic solution. This effect could be attributed to the electrostatic effect interaction between membrane material and rejected ions. In conclusion, this study proved that NF membrane especially the TFC-SR3 membrane successfully treated local groundwater sources for public drinking water supply in line with the WHO standard.

Keywords

iron and manganese;drinking water;groundwater treatment;membrane filtration

References

  1. Abdul Kadir, A., Othman, N. and Azmi, N.A.M. (2012), "Potential of using rosa centifolia to remove iron and manganese in groundwater treatment", Int. J. Sustain. Construct. Eng. Technol., 3(2), 70-82.
  2. Ahmad, A.L., Ooi, B.S., Mohammad, A.W. and Choudhury, J.P. (2004), "Development of a highly hydrophilic nanofiltration membrane for desalination and water treatment", Desalination, 168, 215-221. https://doi.org/10.1016/j.desal.2004.07.001
  3. Al-Rashdi, B.A.M., Johnson, D.J. and Hilal, N. (2013), "Removal of heavy metal ions by nanofiltration", Desalination, 315, 2-7. https://doi.org/10.1016/j.desal.2012.05.022
  4. Berbenni, P., Pollice, A., Canziani, R., Stabile, L. and Nobili, F. (2000), "Removal of iron and manganese from hydrocarbon-contaminated groundwaters", Bioresour. Technol., 74(2), 109-114. https://doi.org/10.1016/S0960-8524(00)00003-1
  5. Bordoloi, S., Nath, M. and Dutta, R.K. (2013a), "PH-conditioning for simultaneous removal of arsenic and iron ions from groundwater", Process Safety Environ. Protect., 91(5), 405-414. https://doi.org/10.1016/j.psep.2012.10.002
  6. Bordoloi, S., Nath, S.K., Gogoi, S. and Dutta, R.K. (2013b), "Arsenic and iron removal from groundwater by oxidation-coagulation at optimized pH: Laboratory and field studies", J. Hazard. Mater., 260, 618-626. https://doi.org/10.1016/j.jhazmat.2013.06.017
  7. Bruggen, B. and Vandecasteele, C. (2003), "Removal of pollutants from surface water and groundwater by nanofiltration: Overview of possible applications in the drinking water industry", Environ. Pollut., 122(3), 435-445. https://doi.org/10.1016/S0269-7491(02)00308-1
  8. Buffle, J., Zhang, Z. and Startchev, K. (2007), "Metal flux and dynamic speciation at (bio)interfaces. Part I: Critical evaluation and compilation of physico-chemical parameters for complexes with simple ligands and fulvic/humic substances", Environ. Sci. Technol., 41(22), 7609-7620. https://doi.org/10.1021/es070702p
  9. Chaturvedi, S. and Dave, P.N. (2012), "Removal of iron for safe drinking water", Desalination, 303, 1-11. https://doi.org/10.1016/j.desal.2012.07.003
  10. Chaudhuri, M., Sapari, N. and Mohak, S.T. (2008), "Removal of iron from groundwater by direct filtration through coal and carbonaceous shale", Proceedings of International Conference on Construction and Building Technology, Kuala Lumpur, Malaysia, June, pp. 267-272.
  11. Childress, A.E. and Elimelech, M. (2000), "Relating nanofiltration membrane performance to membrane charge (Electrokinetic) characteristics", Environ. Sci. Technol., 34(17), 3710-3716. https://doi.org/10.1021/es0008620
  12. Choo, K.H., Lee, H. and Choi, S.J. (2005), "Iron and manganese removal and membrane fouling during UF in conjunction with prechlorination for drinking water treatment", J. Membr. Sci., 267(1-2), 18-26. https://doi.org/10.1016/j.memsci.2005.05.021
  13. De Munari, A. and Schäfer, A.I. (2010), "Impact of speciation on removal of manganese and organic matter by nanofiltration", J. Water Supply: Res. Technol.-AQUA, 59(2-3), p. 152. https://doi.org/10.2166/aqua.2010.067
  14. De Munari, A., Semiao, A.J.C. and Antizar-Ladislao, B. (2013), "Retention of pesticide endosulfan by nanofiltration: Influence of organic matter-pesticide complexation and solute-membrane interactions", Water Res., 47(10), 3484-3496. https://doi.org/10.1016/j.watres.2013.03.055
  15. Department of Statistics (2013), Current Population Estimates, Malaysia.
  16. Ellis, D., Bouchard, C. and Lantagne, G. (2000), "Removal of iron and manganese from groundwater by oxidation and microfiltration", Desalination, 130(3), 255-264. https://doi.org/10.1016/S0011-9164(00)00090-4
  17. Gherasim, C.V. and Mikulasek, P. (2014), "Influence of operating variables on the removal of heavy metal ions from aqueous solutions by nanofiltration", Desalination, 343, 67-74. https://doi.org/10.1016/j.desal.2013.11.012
  18. Hilal, N., Al-Zoubi, H., Darwish, N.A., Mohammad, A.W. and Abu Arabi, M. (2004), "A comprehensive review of nanofiltration membranes: Treatment, pretreatment, modelling, and atomic force microscopy", Desalination, 170(3), 281-308. https://doi.org/10.1016/j.desal.2004.01.007
  19. Hilal, N., Al-Zoubi, H., Mohammad, A.W. and Darwish, N.A. (2005), "Nanofiltration of highly concentrated salt solutions up to seawater salinity", Desalination, 184(1-3), 315-326. https://doi.org/10.1016/j.desal.2005.02.062
  20. Hussin, N.H., Yusoff, I., Alias, Y., Mohamad, S., Rahim, N.Y. and Ashraf, M.A. (2013), "Ionic liquid as a medium to remove iron and other metal ions: A case study of the North Kelantan Aquifer, Malaysia", Environ. Earth Sci., 71(5), 2105-2113.
  21. Jusoh, A., Cheng, W.H., Low, W.M., Ali, N. and Megat Mohd Noor, M.J. (2005), "Study on the removal of iron and manganese in groundwater by granular activated carbon", Desalination, 182(1-3), 347-353. https://doi.org/10.1016/j.desal.2005.03.022
  22. Jusoh, H., Sapari, N. and Raja Azie, R.Z. (2011), "Removal of iron from groundwater by sulfide precipitation", World Academy of Science, Engineering and Technology, No. 60, 652-658.
  23. Kabsch-Korbutowicz, M. and Winnicki, T. (1996), "Application of modified polysulfone membranes to the treatment of water solutions containing humic substances and metal ions", Desalination, 105(1-2), 41-49. https://doi.org/10.1016/0011-9164(96)00056-2
  24. Kasim, N. and Mohammad, A.W. (2013), "Potential of nanofiltration membrane in groundwater treatment for drinking water resources", Jurnal Teknologi, 4(65), 43-46.
  25. Lin, J.L., Huang, C., Pan, J.R. and Wang, Y.S. (2013), "Fouling mitigation of a dead-end microfiltration by mixing-enhanced preoxidation for Fe and Mn removal from groundwater", Colloids and Surfaces A: Physicochemical and Engineering Aspects, 419, 87-93.
  26. Ma, X., Shang, J., Piao, F. and Wu, W. (2010), "Biological removal of iron, manganese and ammonia nitrogen from low-temperature groundwater using biological aerated filter", 2010 International Conference on E-Product E-Service and E-Entertainment (ICEEE), Henan, China, November.
  27. Malek, M.A., Nor, M.A.M. and Leong, Y.P. (2013), "Water security and its challenges for Malaysia", IOP Conference Series: Earth and Environmental Science, Kuala Lumpur, Malaysia, June, p. 012123.
  28. Marchovecchio, J.E., Botte, S.E. and Freiji, R.H. (2011), "Heavy Metals, Major Metals, Trace Elements", In: Handbook of Water Analysis, CRC Press.
  29. Merrill, R.D, Shamim, A.A., Ali, H., Jahan, N., Labrique, A.B., Christian, P. and West, K.P. (2012), "Groundwater iron assessment and consumption by women in rural northwestern Bangladesh", Int. J. Vitamin Nutrition Res., 82, 5-14. https://doi.org/10.1024/0300-9831/a000089
  30. Mohammad, I.C. and Karim, M.H.A. (2010), Groundwater Availability and Quality in Malaysia, JMG 7.
  31. Mohammad, A.W., Othaman, R. and Hilal, N. (2004), "Potential use of nanofiltration membranes in treatment of industrial wastewater from Ni-P electroless plating", Desalination, 168, 241-252. https://doi.org/10.1016/j.desal.2004.07.004
  32. Molinari, R., Argurio, P. and Romeo, L. (2001), "Studies on interactions between membranes (RO and NF) and pollutants ($SiO_2$, $NO_3^−$, $Mn^{2+}$ and humic acid) in water", Desalination, 138(1-3), 271-281. https://doi.org/10.1016/S0011-9164(01)00273-9
  33. Nguyen, C.M., Bang, S., Cho, J. and Kim, K.-W. (2009), "Performance and mechanism of arsenic removal from water by a nanofiltration membrane", Desalination, 245(1-3), 82-94. https://doi.org/10.1016/j.desal.2008.04.047
  34. Pacini, V.A., Ingallinella, A.M. and Sanguinetti, G. (2005), "Removal of iron and manganese using biological roughing up flow filtration technology", Water Res., 39(18), 4463-4475. https://doi.org/10.1016/j.watres.2005.08.027
  35. Peeters, J.M.M., Boom, J.P., Mulder, M.H.V. and Strathmann, H. (1998), "Retention measurements of nanofiltration membranes with electrolyte solutions", J. Membr. Sci., 145(2), 199-209. https://doi.org/10.1016/S0376-7388(98)00079-9
  36. Potgieter, J.H, Mccrindle, R.I., Sihlali, Z., Schwarzer, R. and Basson, N. (2004a), "Removal of iron and manganese from water with a high organic carbon loading. Part i: The effect of various coagulants", WaterAir Soil Pollut., 162, 49-59.
  37. Potgieter, J.H., Modise, J. and Basson, N. (2004b), "Removal of iron and manganese from water with a high organic carbon loading. Part ii: The effect of various adsorbents and nanofiltration membranes", Water Air Soil Pollut., 162, 61-70.
  38. Qin, J., Oo, M. and Kekre, K. (2007), "Nanofiltration for recovering wastewater from a specific dyeing facility", Separ. Purif. Technol., 56(2), 199-203. https://doi.org/10.1016/j.seppur.2007.02.002
  39. Seidel, A., Waypa, J. and Elimelech, M. (2001), "Role of charge (Donnan) exclusion in removal of arsenic from water by a negatively charged porous nanofiltration membrane", Environ. Eng. Sci., 18(2), 105-113. https://doi.org/10.1089/10928750151132311
  40. Sharma, S.K., Petrusevski, B. and Schippers, J.C. (2005), "Biological iron removal from groundwater: A review", J. Water Supply: Res. Technol.-AQUA, 54(4), 239-247.
  41. Sim, S.J., Kang, C.D., Lee, J.W. and Kim, W.S. (2001), "Treatment of highly polluted groundwater by novel iron removal process", J. Environ. Sci. Health, Part A. Toxic/Hazardous Substan. Environ. Eng., 36(1), 25-38. https://doi.org/10.1081/ESE-100000469
  42. SMHB (2000), Kajian Sumber Air Negara 2000-2050 (Semenanjung Malaysia), In: Jilid 4.
  43. Teng, Z., Yuan Huang, J., Fujita, K. and Takizawa, S. (2001), "Manganese removal by hollow fiber microfilter. Membrane separation for drinking water", Desalination, 139(1-3), 411-418. https://doi.org/10.1016/S0011-9164(01)00342-3
  44. Van Halem, D., Olivero, S., de Vet, W.W.J.M., Verberk, J.Q.J.C., Amy, G.L. and van Dijk, J.C. (2010), "Subsurface iron and arsenic removal for shallow tube well drinking water supply in rural Bangladesh", Water Res., 44(19), 5761-5769. https://doi.org/10.1016/j.watres.2010.05.049
  45. Waite, T.D. (2005), "Chemical Speciation Effects in Nanofiltration Separation", In: Nanofiltration- Principles and Applications, (Edited by A.I. Schäfer, A.G. Fane, T.D. Waite), pp. 148-168.
  46. WHO (2008), Guidelines for Drinking-Water Quality, In: Reccomendations, (Volume 1, 3rd Ed.), World Health Organization, Geneva, Switzerland, 390 p.

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Acknowledgement

Supported by : Universiti Kebangsaan Malaysia