Elastomers and Composites (엘라스토머 및 콤포지트)

The Rubber Society of Korea (한국고무학회)
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Synthesis of Copoly(amide-imide)s Based on Silica Nano Particles-polyacrylamide

  • Received : 2016.05.25
  • Accepted : 2016.06.09
  • Published : 2016.06.30

Abstract

It is an inconvenience for silica nano-particles to dry again when using it in that they cohere each other through moisture in the air. Acrylamide groups were introduced to improve such inconvenience and copolymerized with silica nano-particles and then we copolymerized again with polyamic acid in order to increase thermal characteristic. Amide block copolymers were prepared using silica and (3-mercaptopropyl) trimethoxysilane (MPTMS) with a siloxane group, using 2,6-Lutidine as a catalyst. Amide block polymers and copolymers were synthesized via ATRP after brominating pyromellitic dianhydride (PMDA) and polyamic acid of methylene diphenyl diamine (MDA), using ${\alpha}$-bromo isobutyryl bromide. Characteristic peaks of copolymer with amide and imide groups and patterns of amorphous polymers were researched by FT-IR and XRD analyses and the analysis of surface characteristic groups was conducted via XPS. A change in thermal properties was examined through DSC and TGA and solubility for solvents was also researched.

Keywords

PAI;poly(amic acid);siloxane group;DABCO;MPTMS

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Acknowledgement

Supported by : 부경대학교