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Hydrolysable Tannins from Cercidiphyllum japonicum Bark

Lee, Min-Sung;Min, Hee-Jeong;Si, Chuan-Ling;Bae, Young-Soo

  • Received : 2016.06.01
  • Accepted : 2016.07.07
  • Published : 2016.07.25

Abstract

The EtOAc and $H_2O$ soluble fractions of Katsura tree (Cercidiphyllum japonicum Sieb. Et Zucc) bark extracts were chromatographed on a Sephadex LH-20 column with various aqueous MeOH. Gallic acid (1), methyl galate (2), kurigalin (3), 1,2,3,6-tetra-O-galloyl-${\beta}$-D-glucose (4) and 1,2,3,4,6-penta-O-galloyl-${\beta}$-D-glucose (5) were isolated from EtOAc fraction. Isocorilagin (6) and methyl galate (2) were separated from $H_2O$ fraction. The structure determination was done by $^1H$ and $^{13}C$ NMR. Of these isolated compounds, methyl galate (2), kurigalin (3) and isocorilagin (6) were isolated, for the first time, from the bark extracts of Cercidiphyllum japonicum.

Keywords

Katsura tree (Cercidiphyllum japonicum) bark;Hydrolysable tannins;gallotannin;ellagitannin;column chromatography

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Cited by

  1. Extractives of Cercidiphyllum japonicum twigs: isolation and structural elucidation of a new galloylflavonol glycoside, anomeric tannins and flavonoids vol.72, pp.9, 2018, https://doi.org/10.1515/hf-2018-0029
  2. Chemical Constituents of the Flowers of Cercidiphyllum japonicum pp.1573-8388, 2019, https://doi.org/10.1007/s10600-019-02638-2

Acknowledgement

Supported by : Forest Science of Korean Forest Service