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Simultaneous determination of bisphenol A, chlorophenols and alkylphenols by solid-phase extraction and HPLC

  • Lee, Taejoon (Gangwon-do Institute of Health and Environment) ;
  • Park, Keun-Young (Gangwon-do Institute of Health and Environment) ;
  • Pyo, Dongjin (Department of Chemistry, Kangwon National University)
  • Received : 2016.10.28
  • Accepted : 2017.02.05
  • Published : 2017.02.25

Abstract

An analytical method for determining potential endocrine disruptors (bisphenol A, 2-chlorophenol, 2,4-dichlorophenol, 2,4,6-trichlorophenol, pentachlorophenol, p-t-butylphenol, p-pentylphenol, p-hexylphenol, p-t-octylphenol, p-heptylphenol, nonylphenol) by solid-phase extraction (SPE) and High Perfomance Liquid Chromatography(HPLC) equipped with fluorescence and variable wavelength detector has been developed. The SPE process for sample concentration was performed on a commercially available Oasis HLB cartridge packed with polymeric sorbents. The effect of elution solvent and elution volume on the recoveries of the analytes were investigated with HPLC. Average recovery of >85% was achieved with 60mg sorbents using 5mL of methanol as elution solvent. Phenolic compounds in canned drinks, beverages and water samples were surveyed by this proposed method.

Keywords

bisphenol A;alkylphenols;chlorophenols;high performance liquid chromathgraphy (HPLC);solid phase extraction (SPE)

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