DOI QR코드

DOI QR Code

Synthesis and Adhesion Properties of Waterborne Polyurethane Adhesives for Footwear according to Polyol Blending

  • Choi, Min Ji (Polymer Surface Research Division, Korea Institute of Footwear and Leather Technology (KIFLT)) ;
  • Jeong, Boo Young (Polymer Surface Research Division, Korea Institute of Footwear and Leather Technology (KIFLT)) ;
  • Cheon, Jung Mi (Polymer Surface Research Division, Korea Institute of Footwear and Leather Technology (KIFLT)) ;
  • Chun, Jae Hwan (Polymer Surface Research Division, Korea Institute of Footwear and Leather Technology (KIFLT))
  • Received : 2017.03.10
  • Accepted : 2017.03.28
  • Published : 2017.03.31

Abstract

In order to improve the water resistance, we synthesized waterborne polyurethane by using polyester polyol, poly(propylene carbonate) (PPC), 4,4'-dicyclohexylmethane diisocyanate ($H_{12}MDI$), and dimethylolpropionic acid (DMPA). The properties of the synthesized waterborne polyurethane using poly(propylene carbonate) (WPUP) were evaluated by FT-IR, $^1H-NMR$, GPC, DSC, TGA, and UTM. The mechanical properties increased while the adhesion properties decreased with the increase in the amount of PPC. The highest water resistance was shown when the ratio of polyester polyol to PPC was 9:1.

References

  1. K. H. Jin and U. R. Cho, Elastomers and Composites, 49, 31 (2014). https://doi.org/10.7473/EC.2014.49.1.31
  2. H. J. Kim, Rubber Technology, 4, 77 (2003).
  3. Mark F. Sonnenschein, "Polyurethanes (Science, Technology, Markets, and Trends)", 1, 10, John Wile & Sonslnc (2014).
  4. S. M. Kim, N. S. Kwak, Y. K. Yang, B. K. Yim, B. Y. Park, and T. S. Hwang, Polymer (Korea), 29, 253 (2005).
  5. C. Y. Park, Elastomers and Composites, 49, 245 (2014). https://doi.org/10.7473/EC.2014.49.3.245
  6. K. J. Ryu and C. Y. Park, Journal of Environmental Science International, 23, 1909 (2011).
  7. Y. S. Chun, Y. K. Hong, and K. H. Chung, J. of Korean Ind. Eng. Chemistry, 7, 194 (1996).
  8. J. S. Youm and H. J. Kang, Polymer (Korea), 36, 119 (2011).
  9. Y. M. Lee, J. C. Lee, and B. K. Kim, Polymer (Korea), 35, 1005 (1994).
  10. S. Choi, S. T. Noh, and B. B. Choi, J. Ind. Eng. Chem., 5, 52 (1999).
  11. K. C. Frisch and D. Kempner, Eds, Advances in Urethane Science and Technology, 10, 121 (1987).
  12. R. Buscalla, T. Coner, and J. F. Stageman, Polymer Colloids, Elsevier, New York.
  13. Y. W. Chang, J. B. Kim, K. H. Chung, Y. S. Chun, and J. S. Jung, Elastomer, 33, 267 (1998).
  14. S. H. Shin, Synthesis and properties of Polyurethane Dispersion containing Monomeric Diol (2010).
  15. K. H. Kim, K. J. Ha, J. P. Wu, H. S. Park, and K. S. Kwon, Korea J. Oil Fat Chem., 1, 29 (1998).
  16. D. J. Lee and H. D. Kim, J. Korean Fiber Soc., 36, 873 (1999).
  17. S. H. Lee, Anish Cyriac, J. Y. Jeon, and B. Y. Lee, Clean Technology, 17, 244 (2011).
  18. D. I. Lim, J. S. Park, J. H. Park, J. C. Knowles, and M. S. Gong, Journal of Bioactive and Compatible Polymers, 28, 274 (2013). https://doi.org/10.1177/0883911513484572
  19. T. K. Kwe, J. Appl. Polym. Sci., 27, 2891 (1982). https://doi.org/10.1002/app.1982.070270815
  20. J. B. Ahn, H. K. Cho, C. N. Jeong, and S. T. Nho, J. of Korean Ind. Eng. Chem., 8, 230 (1989).
  21. A. W. McLennaghan and R. A. Petherick, Eur. Polym. J., 24, 1063 (1988). https://doi.org/10.1016/0014-3057(88)90066-3
  22. J. C. Lee and B. K. Kim, Polymer, 19, 223 (1995).
  23. H. X. Xiao, K. C. Frisch, and N. MAlwitz, J. Appl. Polym. Sci., 54, 1643 (1994). https://doi.org/10.1002/app.1994.070541107
  24. A. Eceiza, M. D. Martin, K. de la Caba, G. Kortaberria, N. Gabilondo, M. A. Corcuera, and I. Mondragon, Polym. Eng. Sci., 48, 297 (2008). https://doi.org/10.1002/pen.20905