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Rapid and Efficient Debromination of vic-Dibromides with VCl3/Indium System

  • Yoo, Byung Woo (Department of Advanced Materials Chemistry, Korea University) ;
  • Park, Jee Yeon (Department of Advanced Materials Chemistry, Korea University) ;
  • Shin, Hyo Jong (Department of Advanced Materials Chemistry, Korea University)
  • Received : 2018.02.28
  • Accepted : 2018.05.14
  • Published : 2018.08.20

Abstract

The $VCl_3$/In system was found to be a new protocol for debromination of a variety of vic-dibromides to the corresponding alkenes in high yields with short reaction times under mild conditions. This new methodology is highly chemoselective, tolerating several functional groups such as chloro, bromo, fluoro, keto, ester, carboxyl, and methoxy groups.

Keywords

Debromination;vic-Dibromide;Vanadium(III) chloride;Indium

Acknowledgement

Supported by : Korea University

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